catalyst: K2CO3/Norit RX extra in gas Kinetics; (13)CO2/(12)CO/He feed flow, 950 K, pressure of CO or CO2: 7-67 kPa, other reactand pressure keeping constant;
cis-{Os(2,2'-bipyridine)2(CO)(2)H} hexafluorophosphate in water; acetonitrile Kinetics; Electrolysis; Sustained electrolysis of solns. of complex in CO2-satd. CH3CN with added H2O at potentials of -1.4 to -1.6 V at a Pt mesh working electrode.;
参考文献
Organometallics, , vol. 7, p. 238 - 240
→
反应条件
in THF-d8 (tetrahydrofuran-d8) introducing (13)CO2 to soln. of copper compd. in THF-d8 at -80°C in NMR tube, gradual warming to -40°C for 30 min; NMR detection;
参考文献
Journal of the American Chemical Society, , vol. 127, # 49 p. 17196 - 17197
catalyst: 2percent Pt/CeO2 in neat (no solvent) study on pulse-response temporal analysis of products in reverse water-gas shift reaction, as expected no CO observed when H2 pulsed alone;
参考文献
Goguet; Shekhtman; Burch; Hardacre; Meunier; Yablonsky
Journal of Catalysis, 2006 , vol. 237, # 1 p. 102 - 110
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反应条件
in neat (no solvent) Irradiation (UV/VIS); a soln. of complex photolysed, reacted with (13)CO2, monitored by NMR, FTIR and GC; not isolated;
参考文献
Journal of the American Chemical Society, , vol. 125, # 39 p. 11976 - 11987
