water in neat (no solvent) Irradiation (UV/VIS); 750 Torr (13)CO2 gas was loaded into ZrCu(I)-MCM-41 sieve; Zr-O-Cu(I)-MMCT irradiated at 355 nm (110 mW cm**-2 ) for 2.5 h; monitored by IR spectroscopy;
参考文献
Journal of the American Chemical Society, , vol. 127, # 6 p. 1610 - 1611
catalyst: 2percent Pt/CeO2 in neat (no solvent) Kinetics; study on pulse-response temporal analysis of products in reverse water-gas shift reaction when (13)CO2 repeatedly pulsed followed by H2 pulse;
参考文献
Journal of Catalysis, , vol. 237, # 1 p. 102 - 110
(HOCH2CH2N)3N; [Ru(2,2′-bipyridine)3]2+; Co(2,2’-bipyridine)3Cl2 in N,N-dimethyl-formamide Irradiation (UV/VIS); 30 ° C, irradn. for 15 h, DMF/amine 2:1; gas analysed by GC;
in neat (no solvent) byproducts: (13)CH4; complex and acid were mixed at -196°C (vac., N2); warming to room temp., react. for 3 d; chromy. on silica gel;
参考文献
Journal of the American Chemical Society, , vol. 104, p. 5630 - 5633
