(2E,4E,6E,8E,10E,12E)-2,7,11-三甲基-13-(2,6,6-三甲基-1-环己烯-1-基)-2,4,6,8,10,12-十三六烯醛合成路线 （共 6 条）
1638-05-7(2E,4E,6E,8E,10E,12E)-2,7,11-三甲基-13-(2,6,6-三甲基-1-环己烯-1-基)-2,4,6,8,10,12-十三六烯醛+
→
反应条件
(+/-)-2-Ethyloxirane in ethanol RefluxInert atmosphere;
参考文献
University of Maryland, College Park
Patent: US8222458 B2, 2012 ;
Location in patent: Page/Page column 28 ;
1638-05-7(2E,4E,6E,8E,10E,12E)-2,7,11-三甲基-13-(2,6,6-三甲基-1-环己烯-1-基)-2,4,6,8,10,12-十三六烯醛+
→
反应条件
(+/-)-2-Ethyloxirane in ethanol 6 h; Inert atmosphereReflux; optical yield given as percent ee;
参考文献
Khachik, Frederick; Chang, An-Ni
Synthesis, 2011 , # 3 art. no. M07010SS, p. 509 - 516
1638-05-7(2E,4E,6E,8E,10E,12E)-2,7,11-三甲基-13-(2,6,6-三甲基-1-环己烯-1-基)-2,4,6,8,10,12-十三六烯醛
→
反应条件
dihydrogen peroxide; sodium acetate in water T=27°C; pH=5; 1 h; Enzymatic reaction;
参考文献
Zelena, Kateryna; Hardebusch, Bjoern; Huelsdau, Baerbel; Berger, Ralf G.; Zorn, Holger
Journal of Agricultural and Food Chemistry, 2009 , vol. 57, # 21 p. 9951 - 9955
1638-05-7(2E,4E,6E,8E,10E,12E)-2,7,11-三甲基-13-(2,6,6-三甲基-1-环己烯-1-基)-2,4,6,8,10,12-十三六烯醛
→
反应条件
dihydrogen peroxide; sodium acetate in water T=27°C; pH=5; 1 h; Enzymatic reaction;
参考文献
Zelena, Kateryna; Hardebusch, Bjoern; Huelsdau, Baerbel; Berger, Ralf G.; Zorn, Holger
Journal of Agricultural and Food Chemistry, 2009 , vol. 57, # 21 p. 9951 - 9955
1638-05-7(2E,4E,6E,8E,10E,12E)-2,7,11-三甲基-13-(2,6,6-三甲基-1-环己烯-1-基)-2,4,6,8,10,12-十三六烯醛
→
反应条件
dihydrogen peroxide; sodium acetate in water T=27°C; pH=5; 1 h; Enzymatic reaction;
参考文献
Zelena, Kateryna; Hardebusch, Bjoern; Huelsdau, Baerbel; Berger, Ralf G.; Zorn, Holger
Journal of Agricultural and Food Chemistry, 2009 , vol. 57, # 21 p. 9951 - 9955
1638-05-7(2E,4E,6E,8E,10E,12E)-2,7,11-三甲基-13-(2,6,6-三甲基-1-环己烯-1-基)-2,4,6,8,10,12-十三六烯醛
→
反应条件
(+/-)-2-Ethyloxirane in ethanol 6 h; Inert atmosphereReflux; optical yield given as percent ee;
参考文献
Synthesis, , # 3 art. no. M07010SS, p. 509 - 516
