in gas byproducts: ethane, ethene; Irradiation (UV/VIS); laser-induced photolytic chemical vapour deposition (LPCVD) of (C2H5)2GeH2 (2.7 kPa) at 193 nm and deposition of Ge on a reactor NaCl window;; IR and energy-dispersive X-ray spectroscopy;;
参考文献
Pola, Josef; Parsons, Jonathan P.; Taylor, Roger
Journal of the Chemical Society, Faraday Transactions, 1992 , vol. 88, # 12 p. 1637 - 1642
lithium aluminium tetrahydride in diethyl ether
Ge compd. soln. added to excess of LiAlH4 in Et2O, refluxed for 2 h; hydrolyzed, extd. (Et2O), dried (Na2SO4), distd.;
参考文献
Escudie, Jean; Couret, Claude; Satge, Jacques; Andriamizaka, Jean Dominique
Organometallics, 1982 , vol. 1, p. 1261 - 1265
water in N,N,N',N',N'',N''-hexamethylphosphoric triamide
Equimolar mixt. of Et3GeLi and Me3SiGeEt2Li in HMPA is stirred for 94 h at 25°C, then Me3SiCl and water are added.; extn. with ether;
参考文献
Pigarev, S. D.; Bravo-Zhivotovskii, D. A.; Kalikhman, I. D.; Vyazankin, N. S.; Voronkov, M. G.
Journal of Organometallic Chemistry, 1989 , vol. 369, p. 29 - 42
Bravo-Zhivotovskii, D. A.; Pigarev, S. D.; Voronkov, M. G.; Vyazankin, N. S.
Journal of General Chemistry USSR (English Translation), 1989 , vol. 59, p. 761 - 763
Zhurnal Obshchei Khimii, 1989 , vol. 59, p. 863 - 865
lithium aluminium tetrahydride in anhydrous butyl ether
see ref.: Inorganic Synthesis, Jolly W.L., Ed., New York: McGraw-Hill, 1968, p. 176.; gas chromy.;
参考文献
Becerra, Rosa; Boganov, Sergey E.; Egorov, Mikhail P.; Krylova, Irina V.; Nefedov, Oleg M.; Walsh, Robin
Journal of Physical Chemistry A, 2007 , vol. 111, # 8 p. 1434 - 1440
water in N,N,N',N',N'',N''-hexamethylphosphoric triamide
Equimolar mixt. of Et3GeLi and Me3SiGeEt2Li in HMPA is stirred for 94 h at 25°C, then Me3SiCl and water are added.; extn. with ether;
参考文献
Pigarev, S. D.; Bravo-Zhivotovskii, D. A.; Kalikhman, I. D.; Vyazankin, N. S.; Voronkov, M. G.
Journal of Organometallic Chemistry, 1989 , vol. 369, p. 29 - 42
