water in ethanol pH=2.47; Phosphoric acid buffer; Rate constant;

water in phosphate buffer; ethanol T=25°C; pH=2.47; Kinetics; Further Variations:pH-values;

1: 95 percent / 40 aq. percent NaOH, trimethylbenzylammonium chloride / benzene / 17 h / Heating 2: 75 percent / H2 / 10 percent Pd-C / ethanol 3: 72 percent / triethylamine / benzene / 3 h 4: NaOEt / ethanol / 20 h / Heating 5: H2O; acetonitrile / 2 h / Heating 6: 66 percent / triethylamine, toluene-p-sulphonyl azide / acetonitrile / 1.) 0 deg C, 1 h, 2.) RT, 2 h 7: 50 percent / H2O / diethyl ether / 0.75 h / Irradiation 8: 80 percent / toluene / 2 h / Heating 9: 85 percent / diborane-THF complex / 2 h / Heating View Scheme

triethylamine 0.5 h; Heating;

triethylamine 0.5 h; Heating;

lead(IV) acetate in dichloromethane 3 h; Ambient temperature;

triethylamine 0.5 h; Heating;

triethylamine 0.5 h; Heating;

1: 95 percent / 40 aq. percent NaOH, trimethylbenzylammonium chloride / benzene / 17 h / Heating 2: 75 percent / H2 / 10 percent Pd-C / ethanol 3: 72 percent / triethylamine / benzene / 3 h 4: NaOEt / ethanol / 20 h / Heating 5: H2O; acetonitrile / 2 h / Heating 6: 66 percent / triethylamine, toluene-p-sulphonyl azide / acetonitrile / 1.) 0 deg C, 1 h, 2.) RT, 2 h View Scheme

1: 88 percent / trimethylbenzylammonium chloride, 40 percent aq. NaOH / benzene / 9 h / Heating 2: 86 percent / H2 / 10 percent Pd-C / ethanol 3: 84 percent / triethylamine / benzene / 12 h / Ambient temperature 4: NaOEt / ethanol / 5 h / Heating 5: acetonitrile; H2O / 5 h / Heating View Scheme