[Fe(phen)3]3+ in acetonitrile
Ambient temperatureone-electron transfer oxidation; product determined by 1H NMR; add. of O2: t-BuO2 radical determined by ESR; Mechanism;
in water
T=30°C; pH 7 (buffer), μ = 0.1 (KCl), further pH; Rate constant;
参考文献
Shinkai, Seiji; Kawanabe, Sayuri; Kawase, Akito; Yamaguchi, Toshiro; Manabe, Osamu; et al.
Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 6 p. 2095 - 2102
