(2Z)-戊-2,4-二烯腈合成路线 （共 25 条）
反应条件
sodium ethanolate in ethanol T=20°C;
参考文献
Hughes, Simon; Griffiths, Gwerydd; Stirling, Charles J. M.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 1253 - 1264
反应条件
1: 40 percent / n-butyl-lithium / tetrahydrofuran / 1 h / -30 °C 2: 57 percent / thionyl chloride, pyridine / CH2Cl2 / 2 h / Heating 3: 99 percent / methanol / 16 h / Heating 4: 99 percent / H2O2 / ammonium molibdate / methanol 5: 1 M sodium ethoxide / ethanol / 20 °C View Scheme
参考文献
Hughes, Simon; Griffiths, Gwerydd; Stirling, Charles J. M.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 1253 - 1264
反应条件
1: 74 percent / m-chloroperbenzoic acid / CHCl3 / 16 h / 20 °C 2: 40 percent / n-butyl-lithium / tetrahydrofuran / 1 h / -30 °C 3: 57 percent / thionyl chloride, pyridine / CH2Cl2 / 2 h / Heating 4: 99 percent / methanol / 16 h / Heating 5: 99 percent / H2O2 / ammonium molibdate / methanol 6: 1 M sodium ethoxide / ethanol / 20 °C View Scheme
参考文献
Hughes, Simon; Griffiths, Gwerydd; Stirling, Charles J. M.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 1253 - 1264
反应条件
1: 57 percent / thionyl chloride, pyridine / CH2Cl2 / 2 h / Heating 2: 99 percent / methanol / 16 h / Heating 3: 99 percent / H2O2 / ammonium molibdate / methanol 4: 1 M sodium ethoxide / ethanol / 20 °C View Scheme
参考文献
Hughes, Simon; Griffiths, Gwerydd; Stirling, Charles J. M.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 1253 - 1264
反应条件
1: 99 percent / methanol / 16 h / Heating 2: 99 percent / H2O2 / ammonium molibdate / methanol 3: 1 M sodium ethoxide / ethanol / 20 °C View Scheme
参考文献
Hughes, Simon; Griffiths, Gwerydd; Stirling, Charles J. M.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1987 , p. 1253 - 1264
参考文献
Lespagnol,A. et al.
Bulletin de la Societe Chimique de France, 1960 , p. 1162 - 1165
反应条件
T=450°C; Leiten ueber einen Aluminiumsulfat enthaltenden Aluminiumphosphat-Katalysator;
参考文献
Du Pont de Nemours and Co.
Patent: US2334192 , 1941 ;
反应条件
1: Edukt1 ist Gemische der Stereoisomeren 2: nickel /Fuller's earth; ammonia; methanol / Hydrogenation View Scheme
参考文献
Lespagnol,A. et al.
Bulletin de la Societe Chimique de France, 1960 , p. 1162 - 1165
反应条件
tetrahydrofuran; ammonia Hydrieren des Reaktionsgemisches an Raney-Nickel bei 70grad;
参考文献
Kurtz
Justus Liebigs Annalen der Chemie, 1951 , vol. 572, p. 23,56
反应条件
triethylamine in acetonitrile T=40°C; Product distribution / selectivity;
参考文献
Degussa AG
Patent: US2003/212298 A1, 2003 ;
Location in patent: Page/Page column 3 ;
