1-(1-环戊烯基)哌啶合成路线 （共 14 条）
反应条件
Montmorillonite K 10 0.133333 h; microwave (160 Watts) irradiation;
参考文献
Varma, Rajender S.; Dahiya, Rajender; Kumar, Sudhir
Tetrahedron Letters, 1997 , vol. 38, # 12 p. 2039 - 2042
反应条件
toluene-4-sulfonic acid in benzene
参考文献
Starostin, Evgenii K.; Khrustalev, Victor N.; Antipin, Mikhail Yu.; Lalov, Andrei V.
Mendeleev Communications, 2009 , vol. 19, # 6 p. 334 - 336
反应条件
in dichloromethane T=20°C; Michael reaction; 2 h;
参考文献
Molteni, Marco; Consonni, Roberto; Giovenzana, Tommaso; Malpezzi, Luciana; Zanda, Matteo
Journal of Fluorine Chemistry, 2006 , vol. 127, # 7 p. 901 - 908
反应条件
1: 70 percent / dioxane / 8 h 2: 100 percent / LiAlH4 / diethyl ether / 3 h / Ambient temperature 3: oxalic acid / dioxane / 6 h / Heating View Scheme
参考文献
Carlsson, S.; Lawesson, S.-O.
Tetrahedron, 1980 , vol. 36, p. 3585 - 3590
反应条件
hydrogenchloride 1.) benzene, 0 deg C, 48 h, 2.) acetone, 0 deg C; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Gazzetta Chimica Italiana, , vol. 115, # 12 p. 663 - 668
反应条件
in dichloromethane
byproducts: 1-[6-phenyl-bicyclo(3.1.0)hex-1-yl]-piperidine; Ar-atmosphere; addn. of 3 equiv. of piperidine derivative to W-complex soln. (room temp., 1 h); evapn., chromy. (SiO2, petroleum ether/CH2Cl2=9:1);
参考文献
Martin-Vaca, Blanca; Rudler, Henri; Audouin, Max; Nicolas, Muriel; Durand-Reville, Thomas; Vissiere, Brice
Journal of Organometallic Chemistry, 1998 , vol. 567, # 1-2 p. 119 - 126
反应条件
[1,3-diisopropylimidazol-2-ylidene-9-borabicyclo[3.3.1]nonane][tetrakis (pentafluorophenyl)borate]; hydrogen in dichloromethane
T=20°C; P=77525.2 Torr; 4 h; Inert atmosphere;
参考文献
Farrell, Jeffrey M.; Hatnean, Jillian A.; Stephan, Douglas W.
Journal of the American Chemical Society, 2012 , vol. 134, # 38 p. 15728 - 15731,4
反应条件
1: 2) 2 N HCl / 1) acetonitrile, 13 h, reflux, 2) 1 h, reflux
2: 92 percent / p-toluenesulfonic acid / benzene / 12 h / Heating
3: H2, conc. NH3 / Raney-Ni / ethanol / 6 h / 105 - 110 °C / 44130.5 Torr
4: 1) conc. HCl, 2) 2 N NaOH / 1) 2 h, 2) 15 min
5: 3 percent / O2 / methyl acetate / 16 h / Ambient temperature
View Scheme
参考文献
Schumann, Dieter; Naumann, Anneliese
Chemische Berichte, 1982 , vol. 115, # 4 p. 1626 - 1635
反应条件
in ethanol
T=70°C; 2 h;
参考文献
Charushin, Valery N.; van der Plas, Henk C.
Tetrahedron Letters, 1982 , vol. 23, # 38 p. 3965 - 3968
反应条件
acetic acid in 1,4-dioxane
9 h; Heating;
参考文献
Sokolov, V. V.; Potekhin, A. A.; Ovchinnikova, I. V.; Gindin, V. A.; Smirnov, S. N.
Russian Journal of Organic Chemistry, 1994 , vol. 30, # 4 p. 582 - 589
Zhurnal Organicheskoi Khimii, 1994 , vol. 30, # 4 p. 546 - 553
