反,反-1,4-均二苯乙烯合成路线 （共 30 条）
反应条件
1: 1.) NBS, 2.) NaOH, TBAI, H2O / 1.) 50 deg C, 3 h, 2.) benzene, 50 deg C, 5 h 2: 35 percent / HBr, DMSO / 6 h / 125 °C View Scheme
参考文献
Yusubov; Filimonov; Ogorodnikov
Russian Journal of Organic Chemistry, 1998 , vol. 34, # 1 p. 81 - 85
反应条件
Yield given. Multistep reaction;
参考文献
Filimonov, V. D.; Yusubov, M. S.; Ogorodnikov, V. D.
Journal of Organic Chemistry USSR (English Translation), 1989 , vol. 25, # 4.2 p. 753 - 756
Zhurnal Organicheskoi Khimii, 1989 , vol. 25, # 4 p. 838 - 843
反应条件
Yield given. Multistep reaction. Title compound not separated from byproducts;
参考文献
Filimonov, V. D.; Yusubov, M. S.; Ogorodnikov, V. D.
Journal of Organic Chemistry USSR (English Translation), 1989 , vol. 25, # 4.2 p. 753 - 756
Zhurnal Organicheskoi Khimii, 1989 , vol. 25, # 4 p. 838 - 843
反应条件
potassium tert-butylate; bromine 1) CHCl3, 1 h, 2) THF, 30 min, reflux; Yield given. Multistep reaction;
参考文献
Nakatsuji, Shin'ichi; Matsuda, Kosei; Uesugi, Yukiko; Nakashima, Kenichiro; Akiyama, Shuzo; Fabian, Walter
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992 , # 7 p. 755 - 758
反应条件
tri-ruthenium(0)dodecacarbonyl; water; N,N-dimethyl-formamide; triphenylphosphine; trifluoroacetic acid
T=145°C; 3 h; Inert atmosphere; stereoselective reaction;
参考文献
Shen, Ruwei; Chen, Tieqiao; Zhao, Yalei; Qiu, Renhua; Zhou, Yongbo; Yin, Shuangfeng; Wang, Xiangbo; Goto, Midori; Han, Li-Biao
Journal of the American Chemical Society, 2011 , vol. 133, # 42 p. 17037 - 17044
反应条件
bis(η3-allyl-μ-chloropalladium(II)); 4-carboxyphenyldiphenylphosphine; potassium acetate in toluene
T=100°C; Heck reaction;
参考文献
Ooe, Masahiko; Murata, Makoto; Mizugaki, Tomoo; Ebitani, Kohki; Kaneda, Kiyotomi
Journal of the American Chemical Society, 2004 , vol. 126, # 6 p. 1604 - 1605
反应条件
chloro-trimethyl-silane; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran
T=20°C; 8 h;
参考文献
Wang, Jin-Xian; Wang, Kehu; Zhao, Lianbiao; Li, Hongxia; Fu, Ying; Hu, Yulai
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 10-11 p. 1262 - 1270
反应条件
tributyl-amine; PdCl2*4P(o-Tol)3; potassium carbonate in water
T=100°C; 6 h;
参考文献
Bumagin, N. A.; Sukhomlinova, L. I.; Tolstaya, T. P.; Beletskaya, I. P.
Doklady Chemistry, 1993 , vol. 332, # 4 p. 221 - 224
Dokl. Akad. Nauk SSSR Ser. Khim., 1993 , vol. 332, # 4 p. 454 - 456
反应条件
tributyl-amine; potassium carbonate; palladium diacetate in xylene
T=130°C;
参考文献
Luzikova, E. V.; Bumagin, N. A.; Beletskaya, I. P.
Russian Chemical Bulletin, 1993 , vol. 42, # 3 p. 586 - 587
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 3 p. 617
反应条件
trimethylamine-N-oxide; tetrabutyl ammonium fluoride; palladium diacetate in tetrahydrofuran; 1,4-dioxane
T=100°C; Heck-type reaction; 24 h;
参考文献
Inoue, Atsushi; Shinokubo, Hiroshi; Oshima, Koichiro
Journal of the American Chemical Society, 2003 , vol. 125, # 6 p. 1484 - 1485
