1-仲-丁基-2-甲基苯合成路线 （共 25 条）
反应条件
AlCl3, aluminium chloride in dichloromethane T=140°C; Friedel-Crafts Alkylation; 0.0833333 h; Microwave irradiation; Overall yield = 39 percent;
参考文献
Zupp, Laurine R.; Campanella, Veronica L.; Rudzinski, Diandra M.; Beland, Franois; Priefer, Ronny
Tetrahedron Letters, 2012 , vol. 53, # 39 p. 5343 - 5346
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in diethyl ether 20 h; Ambient temperature;
参考文献
Hayashi, Tamio; Konishi, Mitsuo; Kobori, Yuji; Kumada, Makoto; Higuchi, Taiichi; Hirotsu, Ken
Journal of the American Chemical Society, 1984 , vol. 106, p. 158 - 163
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in diethyl ether T=0°C; 8 h;
参考文献
Hayashi, Tamio; Konishi, Mitsuo; Kobori, Yuji; Kumada, Makoto; Higuchi, Taiichi; Hirotsu, Ken
Journal of the American Chemical Society, 1984 , vol. 106, p. 158 - 163
反应条件
1: sec-butylmagnesium chloride With zinc(II) chloride in tetrahydrofuran T=20°C; 0.333333 h; 2: ortho-chlorotoluene With Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran; 1-methyl-pyrrolidin-2-one T=100°C; Negishi reaction; 24 h; Further stages. Title compound not separated from byproducts.;
参考文献
Dai; Fu
Journal of the American Chemical Society, 2001 , vol. 123, # 12 p. 2719 - 2724
反应条件
iron (III) acetylacetonate in diethyl ether T=100°C; Kumada coupling reaction; 0.166667 h; Inert atmosphereMicrowave irradiation;
参考文献
Hasan, Kamrul; Dawe, Louise N.; Kozak, Christopher M.
European Journal of Inorganic Chemistry, 2011 , # 29 p. 4610 - 4621
反应条件
hydrogen fluoride T=0°C;
参考文献
Schlatter; Clark
Journal of the American Chemical Society, 1953 , vol. 75, p. 361,362
反应条件
hydrogen fluoride T=0°C;
参考文献
Schlatter; Clark
Journal of the American Chemical Society, 1953 , vol. 75, p. 361,362
反应条件
Me4-DACH; magnesium; cobalt(II) chloride in tetrahydrofuran T=0°C; Inert atmosphere;
参考文献
Czaplik, Waldemar Maximilian; Mayer, Matthias; Jacobi Von Wangelin, Axel
Synlett, 2009 , # 18 p. 2931 - 2934
反应条件
NiCl2((PPh3)P)2 in diethyl ether 20 h; Ambient temperature;
参考文献
Hayashi, Tamio; Konishi, Mitsuo; Kobori, Yuji; Kumada, Makoto; Higuchi, Taiichi; Hirotsu, Ken
Journal of the American Chemical Society, 1984 , vol. 106, p. 158 - 163
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in diethyl ether 19 h; Ambient temperature;
参考文献
Hayashi, Tamio; Konishi, Mitsuo; Kobori, Yuji; Kumada, Makoto; Higuchi, Taiichi; Hirotsu, Ken
Journal of the American Chemical Society, 1984 , vol. 106, p. 158 - 163
