双(1-金刚烷基)氯化磷合成路线 (共 12 条)
反应条件
lithium aluminium tetrahydride in diethyl ether T=20°C; 4 h;
参考文献
Lavrova, E. A.; Koidan, G. N.; Marchenko, A. P.; Pinchuk, A. M.
Russian Journal of General Chemistry, 1994 , vol. 64, # 9.2 p. 1393 - 1394
Zhurnal Obshchei Khimii, 1994 , vol. 64, # 9 p. 1556 - 1557
反应条件
1: 2-iodo-2',4',6'-triisopropyl-3,6-dimethoxybiphenyl With tert.-butyl lithium in toluene; pentane T=-78°C; 0.666667 h; Inert atmosphere; 2: chlorodi-1-adamantylphosphine With copper(l) chloride in toluene; pentane T=-78 - 140°C; 24 h; Inert atmosphere;
参考文献
Su, Mingjuan; Buchwald, Stephen L.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 19 p. 4710 - 4713