1: With trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); sodium acetate in 1-methyl-pyrrolidin-2-one T=140°C; 6 h; 2: With hydrogenchloride; water in 1-methyl-pyrrolidin-2-one
1: With potassium carbonate; Pd-Tedicyp catalyst in N,N-dimethyl-formamide T=110°C; Heck reaction; 20 h; 2: With sodium hydroxide; water in N,N-dimethyl-formamide T=50 - 80°C;
参考文献
Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice
Tetrahedron, 2004 , vol. 60, # 50 p. 11533 - 11540
1: sodium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol; water / 5 h / 100 °C 2: N-bromosuccinmide / dichloromethane / 12 h / Darkness View Scheme
参考文献
Kim, Ran; Lee, Sunghun; Kim, Kwon-Hyeon; Lee, Yun-Ji; Kwon, Soon-Ki; Kim, Jang-Joo; Kim, Yun-Hi
Chemical Communications, 2013 , vol. 49, # 41 p. 4664 - 4666