溴(五氟)-lambda6-硫烷合成路线 （共 7 条）
反应条件
byproducts: SF6, SF4; 150°C, 16 h, procedure described by T. A. Kovacina, A. D. Berry,and W. B. Fox, J. Fluorine Chem., 7,430, (1976); trap-to-trap fractionation (-63°C, -116°C, -196°C), addn. of Hg to the trap at 0°C;
参考文献
Rahbarnoohi, Rahim; Sams, Lewis C.
Inorganic Chemistry, 1983 , vol. 22, p. 840 - 841
反应条件
in neat (no solvent) byproducts: Br2, FNO; Irradiation (UV/VIS); irradiated for 12 h with λmax = 420 nm; condensed into a cylinder held at -196°C, vac. transferred into another cylinder, condensed several times (trap-to-trap); obtained with apurity of ca 98percent;
参考文献
Lu, Norman; Thrasher, Joseph S.; Von Ahsen, Stefan; Willner, Helge; Hnyk, Drahomir; Oberhammer, Heinz
Inorganic Chemistry, 2006 , vol. 45, # 4 p. 1783 - 1788
反应条件
in neat (no solvent) byproducts: Br2, FNO; Irradiation (UV/VIS); irradiated for 12 h with λmax = 420 nm; condensed into a cylinder held at -196°C, vac. transferred into another cylinder, condensed several times (trap-to-trap); obtained with apurity of ca 98percent;
参考文献
Inorganic Chemistry, , vol. 45, # 4 p. 1783 - 1788
参考文献
Kitazume,T.; Shreeve,J.M.
Journal of the American Chemical Society, 1978 , vol. 100, p. 492 - 496
反应条件
in neat (no solvent)
byproducts: Br2, FNO; Irradiation (UV/VIS); irradiated for 12 h with λmax = 420 nm; condensed into a cylinder held at -196°C, vac. transferred into another cylinder, condensed several times (trap-to-trap); obtained with apurity of ca 98percent;
参考文献
Lu, Norman; Thrasher, Joseph S.; Von Ahsen, Stefan; Willner, Helge; Hnyk, Drahomir; Oberhammer, Heinz
Inorganic Chemistry, 2006 , vol. 45, # 4 p. 1783 - 1788
参考文献
Kitazume,T.; Shreeve,J.M.
Journal of the American Chemical Society, 1978 , vol. 100, p. 492 - 496
反应条件
in gaseous matrix
Kinetics; reaction of H (produced on microwave discharge) and SF5Br in Ar; not isolated;
参考文献
Malins, R. J.; Setser, D. W.
Journal of Chemical Physics, 1980 , vol. 73, # 11 p. 5666 - 5680
