2,4,6-三甲基苯硫酚合成路线 （共 29 条）
参考文献
Societe Nationale Elf Aquitaine (Production)
Patent: US5113019 A1, 1992 ;
反应条件
lithium aluminium tetrahydride in diethyl ether 5 h; Heating;
参考文献
Blower, Philip J.; Dilworth, Jonathan R.; Hutchinson, John P.; Zubieta, Jon A.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 1533 - 1542
反应条件
potassium tert-butylate in tetrahydrofuran T=-78°C; 0.166667 h;
参考文献
Becht, Jean-Michel; Wagner, Alain; Mioskowski, Charles
Journal of Organic Chemistry, 2003 , vol. 68, # 14 p. 5758 - 5761
反应条件
chlorosulphuric acid; sulfuric acid; zinc 1) -5 deg C, 2a) ice, 2b) reflux; Multistep reaction;
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 68, # 1-4 p. 261 - 292
反应条件
1.1: Mg / tetrahydrofuran 1.2: 83 percent / tetrahydrofuran; CH2Cl2 / 2 h / 20 °C 2.1: 83 percent / MeLi / 12 h / 0 - 20 °C View Scheme
参考文献
Synlett, , # 17 art. no. G25605ST, p. 2691 - 2693
反应条件
in dichloromethane 0.5 h; Schlenk techniqueGlovebox;
参考文献
Dalton Transactions, , vol. 43, # 11 p. 4483 - 4493
反应条件
sodium hydroxide; benzene diazonium chloride
参考文献
Nakayama, Juzo; Fujita, Toko; Hoshino, Masamatsu
Chemistry Letters, 1983 , p. 249 - 250
反应条件
(i) Cu2O, EtOH, (ii) /BRN= 1524687/, (iii) aq. H2O2, Ac2O, AcOH; Multistep reaction;
参考文献
Truce,W.E.; Guy,M.M.
Journal of Organic Chemistry, 1961 , vol. 26, p. 4331 - 4336
反应条件
d-(+)-α-methylbenzylamine; (-)-Brucine; quinine powder T=0 - 40°C; kinetic resolution of title compound up to 81.8percent e.e. in different solvents and conditions; Product distribution;
参考文献
Dell'Erba, Carlo; Novi, Marino; Garbarino, Giacomo; Corallo, Poluzzi Giancarla
Tetrahedron Letters, 1983 , vol. 24, # 11 p. 1191 - 1192
反应条件
triethylamine in diethyl ether byproducts: 1,2-dimethoxyethane; Cooling of TMTH and NEt3 soln. (-30°C), addn. of Mo(C-t-Bu)Cl3(dme) as solid in small portions, soln. turns yellow, then green as Et3NHClpptd., warming to room temp.; Filtn. through Celite after 2 h, evapn. to dryness in vac., recrystn. from min. amt. of ether (-40°C).;
参考文献
Murdzek, John S.; Blum, Lauren; Schrock, Richard R.
Organometallics, 1988 , vol. 7, p. 436 - 441
