AlCl3 congealing of the products; pumping H2 out; fractionating; transition temp.: -135 - -120 °C (GeH4), -120 - -90 °C (HCl), -83 - -78 °C (H3GeCl) and -61 - -52 °C (H2GeCl2);;
参考文献
Smyth, C. P.
Journal of the American Chemical Society, 1941 , vol. 63, p. 57 - 66
Dennis, L. M.; Judy, P. R.
Journal of the American Chemical Society, 1929 , vol. 51, p. 2324 - 2324
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Gmelin Handbook: Ge: MVol., 15, page 44 - 46
CCl4 in benzene under N2, 3-80 days; detn. by (1)H-NMR;
参考文献
Audett, Judy A. nee Christie; Mackay, Kenneth M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 2635 - 2644
in neat (no solvent) reaction with SnCl4 at room temp. under formation of GeH3Cl; no GeH2Cl2 formed;;
参考文献
Bentham, J. E.; Cradock, S.; Ebsworth, E. A. V.
Inorganic and Nuclear Chemistry Letters, 1971 , vol. 7, p. 1077 - 1079
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Gmelin Handbook: Sn: MVol.C1, 6.9.7.5.10, page 311 - 311
Dennis, L. M.; Judy, P. R.
Journal of the American Chemical Society, 1929 , vol. 51, p. 2324 - 2324
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Gmelin Handbook: Ge: MVol., 15, page 44 - 46
Dennis, L. M.; Judy, P. R.
Journal of the American Chemical Society, 1929 , vol. 51, p. 2324 - 2324
Full Text Show Details
Gmelin Handbook: Ge: MVol., 15, page 44 - 46
Dennis, L. M.; Judy, P. R.
Journal of the American Chemical Society, 1929 , vol. 51, p. 2324 - 2324
Full Text Show Details
Gmelin Handbook: Ge: MVol., 15, page 44 - 46
