(1R,2S,5R)-(-)-薄荷基(S)-对甲苯亚磺酸酯合成路线 （共 50 条）
反应条件
in benzene
0.5 h; Ambient temperature;
参考文献
Drabowicz, Jozef; Bujnicki, Bogdan; Mikolajczyk, Marian
Journal of Organic Chemistry, 1982 , vol. 47, # 17 p. 3325 - 3327
反应条件
1.) RT, 6 h -> -40 deg C, 2.) RT; Yield given. Multistep reaction;
参考文献
Annunziata, Rita; Cinquini, Mauro; Cozzi, Franco
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , p. 339 - 344
反应条件
1.) RT, 6 h -> -40 deg C, 2.) RT; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Annunziata, Rita; Cinquini, Mauro; Cozzi, Franco
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , p. 339 - 344
反应条件
1: 74 percent / n-BuLi / tetrahydrofuran / 1.) -78 deg C, 90 min, 2.) -78 deg C, 15 min
2: 90 percent / cupric sulfate / acetone
View Scheme
参考文献
Posner, Gary H.; Mallamo, John P.; Hulce, Martin; Frye, Leah L.
Journal of the American Chemical Society, 1982 , vol. 104, # 15 p. 4180 - 4185
反应条件
in benzene
0.5 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Drabowicz, Jozef; Bujnicki, Bogdan; Mikolajczyk, Marian
Journal of Organic Chemistry, 1982 , vol. 47, # 17 p. 3325 - 3327
反应条件
1: (i) Mg, (ii) /BRN= 4689107/
2: MCPBA
View Scheme
参考文献
Cinquini,M. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 2061 - 2067
反应条件
1: (i) Mg, (ii) /BRN= 4689107/
2: MCPBA
View Scheme
参考文献
Cinquini,M. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 2061 - 2067
反应条件
in benzene
0.5 h; Ambient temperature;
参考文献
Drabowicz, Jozef; Bujnicki, Bogdan; Mikolajczyk, Marian
Journal of Organic Chemistry, 1982 , vol. 47, # 17 p. 3325 - 3327
反应条件
cesium fluoride; lithium hexamethyldisilazane
1.) THF; 2.) THF; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Davis, Franklin A.; Reddy, Rajarathnam E.; Szewczyk, Joanna M.; Portonovo, Padma S.
Tetrahedron Letters, 1993 , vol. 34, # 39 p. 6229 - 6232
反应条件
1: 1. LiN(C3H7-i)2 / 1.) THF; 2.) THF, -78 deg C, 30 min
2: 90 percent / CuCl2 / tetrahydrofuran; H2O / 25 °C / phosphate buffer
View Scheme
参考文献
Banfi, Luca; Colombo, Lino; Gennari, Cesare; Annunziata, Rita; Cozzi, Franco
Synthesis, 1982 , # 10 p. 829 - 831
