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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
150785-70-9
合成路线
(共 5 条)
150785-70-9
→
反应条件
35853-45-3
4-溴-2,8-二(三氟甲基)喹啉
反应条件
phosphorus; bromine in acetic acid T=25°C; 4 h;
参考文献
Babu, Konda Ramesh; Eeshwaraiah, Begari; Aravind, Dachepally; Meshram, Harshadas M.; Raju, Rallabaldi Madhusudan; Bhattacharya, Apurba; Bandichhor, Rakeshwar
Monatshefte fur Chemie, 2008 , vol. 139, # 2 p. 179 - 181
150785-70-9
→
反应条件
83012-13-9
4-氯-2,8-双(三氟甲基)喹啉
反应条件
acetyl chloride in acetic acid T=25°C; 6 h;
参考文献
Babu, Konda Ramesh; Eeshwaraiah, Begari; Aravind, Dachepally; Meshram, Harshadas M.; Raju, Rallabaldi Madhusudan; Bhattacharya, Apurba; Bandichhor, Rakeshwar
Monatshefte fur Chemie, 2008 , vol. 139, # 2 p. 179 - 181
150785-70-9
+
7486-35-3
三丁基乙烯基锡
→
反应条件
1031928-53-6
反应条件
bis-triphenylphosphine-palladium(II) chloride; tetrabutylammomium bromide; potassium carbonate in acetonitrile T=90°C; Stille coupling; 4 h; Inert atmosphereSealed tube;
参考文献
Jonet, Alexia; Dassonville-Klimpt, Alexandra; Da Nascimento, Sophie; Leger, Jean-Michel; Guillon, Jean; Sonnet, Pascal
Tetrahedron Asymmetry, 2011 , vol. 22, # 2 p. 138 - 148
150785-70-9
→
反应条件
150785-69-6
反应条件
phosphorus; iodine in acetic acid T=140°C; 7 h;
参考文献
Meshram, H. M.; Chennakesava Reddy, B.; Aravind Kumar, D.; Kalyan, M.; Ramesh, P.; Kavitha, P.; Venkateswara Rao, J.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 2012 , vol. 51, # 9 p. 1411 - 1416,6
150785-70-9
→
反应条件
57120-54-4
2-[2,8-二(三氟甲基)-4-喹啉基]环氧乙烷
反应条件
1: bis-triphenylphosphine-palladium(II) chloride; tetrabutylammomium bromide; potassium carbonate / acetonitrile / 4 h / 90 °C / Inert atmosphere; Sealed tube 2: MnIII(L-3,5-t-Bu)(Cl); 4-methylmorpholine N-oxide; 3-chloro-benzenecarboperoxoic acid / -78 °C View Scheme
参考文献
Jonet, Alexia; Dassonville-Klimpt, Alexandra; Da Nascimento, Sophie; Leger, Jean-Michel; Guillon, Jean; Sonnet, Pascal
Tetrahedron Asymmetry, 2011 , vol. 22, # 2 p. 138 - 148