hydrogen cation in perchloric acid; nitric acid Kinetics; byproducts: H2O; kinetic investigation of the autocatalytic react. at 25°C, pH 0.4-2.5, investigation of influemce of chlorite- and bromide-concn., discussion of mechanism;; not isolated, monitoring of react. by UV (390nm, production of Br2) andpotentiometric measurements;;
参考文献
Simoyi, Reuben H.
Journal of Physical Chemistry, 1985 , vol. 89, # 16 p. 3570 - 3574
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反应条件
in water Kinetics;
参考文献
Umile, Thomas P.; Wang, Dong; Groves, John T.
Inorganic Chemistry, 2011 , vol. 50, # 20 p. 10353 - 10362
Levi, G. R.; Tabet, M.
Gazzetta Chimica Italiana, 1935 , vol. 65, p. 1138 - 1144
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Gmelin Handbook: Cl: SVol.B2, 8, page 331 - 333
acetic acid-sodium acetate in water Kinetics; react. of S4O6(2-) and ClO2(1-) in acetic acid-Na acetate, 0.5 M ionic strength, pH 4.95; monitored spectrophotometrically;
参考文献
Horvath, Attila K.; Nagypal, Istvan; Peintler, Gabor; Epstein, Irving R.
Journal of the American Chemical Society, 2004 , vol. 126, # 20 p. 6246 - 6247