6-(乙基亚磺酰)-2,2'-联吡啶合成路线 （共 9 条）
反应条件
magnesium monoperoxyphthalate hexahydrate in methanol Ambient temperature;
参考文献
Uenishi, Jun'ichi; Tanaka, Takakazu; Nishiwaki, Kenji; Wakabayashi, Shoji; Oae, Shigeru; Tsukube, Hiroshi
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4382 - 4388
反应条件
1: 1) n-BuLi / 1) Et2O, hexane, THF, -78 deg C, 2) THF, -78 deg C, 5 min 2: 1) NaH / 2) HMPA, r.t., 20 min 3: Mg-monoperoxyphthalate / methanol / 1 h / Ambient temperature View Scheme
参考文献
Uenishi, Jun'ichi; Tanaka, Takakazu; Nishiwaki, Kenji; Wakabayashi, Shoji; Oae, Shigeru; Tsukube, Hiroshi
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4382 - 4388
反应条件
1: 1) n-BuLi / 1) Et2O, hexane, THF, -78 deg C, 2) THF, -78 deg C, 5 min 2: 1) NaH / 2) HMPA, r.t., 20 min 3: Mg-monoperoxyphthalate / methanol / 1 h / Ambient temperature View Scheme
参考文献
Uenishi, Jun'ichi; Tanaka, Takakazu; Nishiwaki, Kenji; Wakabayashi, Shoji; Oae, Shigeru; Tsukube, Hiroshi
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4382 - 4388
反应条件
1: 1) NaH / 2) HMPA, r.t., 20 min 2: Mg-monoperoxyphthalate / methanol / 1 h / Ambient temperature View Scheme
参考文献
Uenishi, Jun'ichi; Tanaka, Takakazu; Nishiwaki, Kenji; Wakabayashi, Shoji; Oae, Shigeru; Tsukube, Hiroshi
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4382 - 4388
反应条件
1: 1) n-BuLi / 1) Et2O or THF, -78 deg C 2: monoperhydroxyphthalic acid magnesium salt / methanol / Ambient temperature View Scheme
参考文献
Uenishi; Tanaka; Wakabayashi; Oae; Tsukube
Tetrahedron Letters, 1990 , vol. 31, # 32 p. 4625 - 4628
反应条件
1: 1) n-BuLi / 1) Et2O or THF, -78 deg C 2: monoperhydroxyphthalic acid magnesium salt / methanol / Ambient temperature View Scheme
参考文献
Uenishi; Tanaka; Wakabayashi; Oae; Tsukube
Tetrahedron Letters, 1990 , vol. 31, # 32 p. 4625 - 4628
反应条件
n-butyllithium 1) Et2O or THF, -78 deg C 2) THF, -78 deg C; Yield given. Multistep reaction;
参考文献
Tetrahedron Letters, , vol. 31, # 32 p. 4625 - 4628
反应条件
1: 1) n-BuLi / 1) Et2O, hexane, THF, -78 deg C, 2) THF, -78 deg C, 5 min
2: 1) n-BuLi / 1) Et2O-hexane-THF, -78 deg C, 5-10 min, 2) -78 deg C
View Scheme
参考文献
Uenishi, Jun'ichi; Tanaka, Takakazu; Nishiwaki, Kenji; Wakabayashi, Shoji; Oae, Shigeru; Tsukube, Hiroshi
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4382 - 4388
反应条件
n-butyllithium
1) Et2O, hexane, THF, -78 deg C, 2) THF, -78 deg C, 5 min; Yield given. Multistep reaction;
参考文献
Uenishi, Jun'ichi; Tanaka, Takakazu; Nishiwaki, Kenji; Wakabayashi, Shoji; Oae, Shigeru; Tsukube, Hiroshi
Journal of Organic Chemistry, 1993 , vol. 58, # 16 p. 4382 - 4388
