(Z)-7-十二碳烯-1-醇乙酸酯合成路线 （共 65 条）
反应条件
1: 55 percent / Li2CuCl4 / tetrahydrofuran / 3 h / -10 °C
2: 54 percent / pyridinium p-toluenesulfonate / methanol / 6 h / 55 °C
3: 82 percent / pyridine / CH2Cl2 / 5 h / Ambient temperature
View Scheme
参考文献
Trehan; Vig; Singh; Sharma; Kad
Indian Journal of Chemistry - Section B Organic Chemistry Including Medicinal Chemistry, 1990 , vol. 29, # 6 p. 518 - 520
反应条件
1: PBr3, LiBr, Py
2: CuCN / dimethylformamide
3: NaBH4, CoCl2*6H2O / ethanol
4: aq. H2SO4, aq. NaNO2
View Scheme
参考文献
Nagarkatti; Ashley
Journal of the Indian Chemical Society, 1978 , vol. 55, # 6 p. 589 - 592
反应条件
1: CuCN / dimethylformamide
2: NaBH4, CoCl2*6H2O / ethanol
3: aq. H2SO4, aq. NaNO2
View Scheme
参考文献
Nagarkatti; Ashley
Journal of the Indian Chemical Society, 1978 , vol. 55, # 6 p. 589 - 592
反应条件
1: NaBH4 / ethanol
2: PBr3, LiBr, Py
3: CuCN / dimethylformamide
4: NaBH4, CoCl2*6H2O / ethanol
5: aq. H2SO4, aq. NaNO2
View Scheme
参考文献
Nagarkatti; Ashley
Journal of the Indian Chemical Society, 1978 , vol. 55, # 6 p. 589 - 592
反应条件
1: NaBH4, CoCl2*6H2O / ethanol
2: aq. H2SO4, aq. NaNO2
View Scheme
参考文献
Nagarkatti; Ashley
Journal of the Indian Chemical Society, 1978 , vol. 55, # 6 p. 589 - 592
反应条件
1: aq. HCl / Heating
2: NaBH4 / ethanol
3: PBr3, LiBr, Py
4: CuCN / dimethylformamide
5: NaBH4, CoCl2*6H2O / ethanol
6: aq. H2SO4, aq. NaNO2
View Scheme
参考文献
Nagarkatti; Ashley
Journal of the Indian Chemical Society, 1978 , vol. 55, # 6 p. 589 - 592
反应条件
sodium iodide in dimethyl sulfoxide
参考文献
Kovaleva,A.S. et al.
Journal of Organic Chemistry USSR (English Translation), 1972 , vol. 8, p. 2523 - 2527
Zhurnal Organicheskoi Khimii, 1972 , vol. 8, p. 2474 - 2479
反应条件
1: 85 percent / pyridine / Ambient temperature
3: 1.) 9-borabicyclo<3.3.1>nonane (9-BBN), 2.) methanol, glacial acetic acid / 1.) THF, 0 deg C, 48 h, 2.) 25 deg C, 1 h
View Scheme
参考文献
Brown, Herbert C.; Wang, Kung K.
Journal of Organic Chemistry, 1986 , vol. 51, # 24 p. 4514 - 4517
反应条件
2: 1.) 9-borabicyclo<3.3.1>nonane (9-BBN), 2.) methanol, glacial acetic acid / 1.) THF, 0 deg C, 48 h, 2.) 25 deg C, 1 h
View Scheme
参考文献
Brown, Herbert C.; Wang, Kung K.
Journal of Organic Chemistry, 1986 , vol. 51, # 24 p. 4514 - 4517
反应条件
2: pyridine
View Scheme
参考文献
Tolstikov, G. A.; Odinokov, V. N.; Galeeva, R. I.; Bakeeva, R. S.; Akhunova, V. R.
Chemistry of Natural Compounds, 1982 , vol. 18, # 2 p. 219 - 224
Khimiya Prirodnykh Soedinenii, 1982 , vol. 18, # 2 p. 239 - 245
