in dimethyl-ether byproducts: (CH3)3NHBr; H2O was added to Me3N*GeH3Br*Me2O in Me2O, mixt. was warmed to -63°C for 4-5 h; volatiles were removed in vac., sepd. by low temp. high-vac. distn.;
参考文献
Heil, Charles A.; Norman, Arlan D.
Inorganica Chimica Acta, 1982 , vol. 64, p. L197 - L198
in dimethyl-ether byproducts: (CH3)3N(2)HBr; MeOH was added to Me3N*GeH3Br*Me2O in Me2O, mixt. was warmed to -63°C for 4-5 h; volatiles were removed in vac., sepd. by low temp. high-vac. distn.;
参考文献
Heil, Charles A.; Norman, Arlan D.
Inorganica Chimica Acta, 1982 , vol. 64, p. L197 - L198
in dimethyl-ether byproducts: (CH3)3NHBr; MeOH was added to Me3N*GeH3Br*Me2O in Me2O, mixt. was warmed to -63°C for 4-5 h; volatiles were removed in vac., sepd. by low temp. high-vac. distn.;
参考文献
Heil, Charles A.; Norman, Arlan D.
Inorganica Chimica Acta, 1982 , vol. 64, p. L197 - L198
byproducts: H2O; passing GeH3Br through Ag2CO3/glass at 25°C or at -28°C, 5 hours;;
参考文献
Srivastava, T. N.; Griffiths, J. E.; OKnyszchuk, M.
Canadian Journal of Chemistry, 1962 , vol. 40, p. 739 - 744
Full Text Show Details
Gmelin Handbook: Ag: MVol.B3, 16.3.1.8.4, page 291 - 293
byproducts: GeH2, H2O; passing GeH3Cl through Ag2CO3/glass at 25°C;;
参考文献
Srivastava, T. N.; Griffiths, J. E.; OKnyszchuk, M.
Canadian Journal of Chemistry, 1962 , vol. 40, p. 739 - 744
Full Text Show Details
Gmelin Handbook: Ag: MVol.B3, 16.3.1.8.4, page 291 - 293
