4,4,5,5,5-五氟戊烷硫醇合成路线 （共 9 条）
反应条件
in N,N-dimethyl acetamide T=80°C; 16 h;
参考文献
US2006/30552 A1, ;
Page/Page column 25 ;
反应条件
triphenylphosphine in tetrahydrofuran
反应条件
sodium hydroxide T=100°C; 3 h;
参考文献
Li, Xun; Provencher, Louis; Singh, Shankar M.
Tetrahedron Letters, 1994 , vol. 35, # 49 p. 9141 - 9144
反应条件
1: 95 percent / hydrogen, triethylamine / platinum oxide / ethyl acetate / 3 h / 25 °C 2: 88 percent / 1.) triphenylphosphine, diisopropyl azodicarboxylate / tetrahydrofuran / 1.) 0 deg C, 30 min; 2.) 0 deg C, 30 min then 25 deg C, 1 h 3: 65 percent / 2N aq. sodium hydroxide / 3 h / 100 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 35, # 49 p. 9141 - 9144
反应条件
1: 88 percent / 1.) triphenylphosphine, diisopropyl azodicarboxylate / tetrahydrofuran / 1.) 0 deg C, 30 min; 2.) 0 deg C, 30 min then 25 deg C, 1 h 2: 65 percent / 2N aq. sodium hydroxide / 3 h / 100 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 35, # 49 p. 9141 - 9144
反应条件
triphenylphosphine in tetrahydrofuran
反应条件
sodium hydroxide in N,N-dimethyl acetamide; water T=20°C; 0.6 h; Product distribution / selectivity;
参考文献
MacDonald, Peter Lindsay; Bigatti, Ettore; Rossetto, Pierluigi
Patent: US2006/30552 A1, 2006 ;
Location in patent: Page/Page column 25 ;
反应条件
sodium hydroxide in N,N-dimethyl acetamide; water 1 h; Product distribution / selectivity;
参考文献
MacDonald, Peter Lindsay; Bigatti, Ettore; Rossetto, Pierluigi
Patent: US2006/30552 A1, 2006 ;
Location in patent: Page/Page column 26 ;
反应条件
sodium hydroxide in N,N-dimethyl acetamide; water
T=20°C; 0.6 h; Product distribution / selectivity;
参考文献
MacDonald, Peter Lindsay; Bigatti, Ettore; Rossetto, Pierluigi
Patent: US2006/30552 A1, 2006 ;
Location in patent: Page/Page column 25 ;
