(1-十六烷基)三苯基溴化磷鎓合成路线 （共 5 条）
参考文献
Zhu, Yingdong; Soroka, Dominique N.; Sang, Shengmin
Journal of Agricultural and Food Chemistry, 2012 , vol. 60, # 35 p. 8624 - 8631
反应条件
n-butyllithium 1.) hexane, THF, 15 min 2.) hexane, THF, 18 h; Multistep reaction. Yields of byproduct given;
参考文献
Jefferson, Alan; Sargent, Melvyn V.; Wangchareontrakul, Sirichai
Australian Journal of Chemistry, 1988 , vol. 41, # 1 p. 19 - 25
反应条件
1: 1.) NaCH2SOMe / 1.) DMSO, 60 deg, 30 min, 2.) DMSO, 50 deg C, overnight
2: H2 / PtO2 / ethyl acetate / 1 h
View Scheme
参考文献
Jinno, Shuji; Okita, Takaaki
Chemical and Pharmaceutical Bulletin, 1998 , vol. 46, # 11 p. 1688 - 1694
反应条件
1: 1.) NaCH2SOMe / 1.) DMSO, 60 deg, 30 min, 2.) DMSO, 50 deg C, overnight
2: H2 / PtO2 / ethyl acetate / 1 h
View Scheme
参考文献
Jefferson, Alan; Sargent, Melvyn V.; Wangchareontrakul, Sirichai
Australian Journal of Chemistry, 1988 , vol. 41, # 1 p. 19 - 25
反应条件
1: CTPB With n-butyllithium in tetrahydrofuran; dimethyl sulfoxide
T=10 - 15°C; 0.0833333 h;
2: pelargonaldehyde in tetrahydrofuran; dimethyl sulfoxide
T=20°C; 0.5 h;
参考文献
Drijfhout, Falko P.; Groot, Astrid T.
Journal of Chemical Ecology, 2001 , vol. 27, # 6 p. 1133 - 1149
