暂无反应条件数据

1: pyridine / 2 h / 70 - 80 °C 2: KOH / pyridine / 80 °C 3: 97 percent / conc. H2SO4, acetic acid / 1 h / 50 °C 4: 56 percent / dimethyldioxirane / acetone / 0 °C 5: 98 percent / K2CO3 / acetone / Heating 6: 85 percent / AlCl3 / acetonitrile / 0.5 h / Ambient temperature 7: 85 percent / K2CO3 / methanol / 1.5 h / Heating 8: 76 percent / H2 / 10percent Pd/C / methanol; ethyl acetate / Ambient temperature View Scheme

1: pyridine / 2 h / 120 °C 2: KOH, pyridine / 4 h / 60 °C 3: 98 percent / sodium acetate / acetic acid / 4 h / 140 °C 4: 80 percent / H2 / 10percent Pd/C / ethyl acetate; methanol 5: AlBr3 / acetonitrile / 50 °C View Scheme

1: pyridine / 2 h / 60 - 80 °C 2: KOH, pyridine / 2 h / 60 - 70 °C 3: H2SO4, AcOH / 1 h / 50 °C 4: 100 percent / N,N-diisopropylethylamine / CH2Cl2 5: 1.) dimethyldioxirane, 2.) TsOH / 1.) acetone, CH2Cl2, 0 deg C, 12 h, 2.) CH2Cl2, 0 deg C, 20 min 6: conc. HCl / acetic acid / 2 h / Ambient temperature 7: K2CO3 / acetone / Heating 8: AlBr3 / acetonitrile / 0.67 h / 0 °C 9: H2 / 10percent Pd/C / methanol; ethyl acetate View Scheme

2,2'-azo-bisisobutyronitrile; trichloromonobromomethane; Fonderma T=100°C; 0.0833333 h; Heating; Yield given. Yields of byproduct given;