二(2-乙基己基)碳酸酯合成路线 （共 11 条）
反应条件
dibutyl-bis(2-ethylhexyloxy)tin; 1,1,3,3-tetrabutyl-1,3-bis(2-ethylhexyloxy)distannoxane in 2-ethyl-n-hexanol T=120°C; P=22502.3 - 26252.6 Torr; 4 h;
参考文献
Asahi Kasei Chemicals Corporation
Patent: EP1460056 A1, 2004 ;
Location in patent: Page 26 ;
反应条件
triphenylphosphine; diethylazodicarboxylate in tetrahydrofuran 18 h;
参考文献
Hoffman, William A.
Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5209 - 5210
反应条件
1,1,3,3-tetrabutyl-1,3-bis(2-ethylhexyloxy)distannoxane T=120°C; P=30003 Torr; 4 h; AutoclaveIndustry scale;
参考文献
Asahi Kasei Chemicals Corporation
Patent: EP2275406 A1, 2011 ;
Location in patent: Page/Page column 44 ;
反应条件
1: 2-ethyl-n-hexanol With pyridine in hexane T=20°C; 2: chloro formic acid 2-ethylhexyl ester in hexane T=80°C; 3.5 h;
参考文献
FUJIFILM Corporation; Omura, Kazufumi; Komori, Yasushi
Patent: US8604233 B2, 2013 ;
Location in patent: Page/Page column 69 ;
反应条件
diisobutylaluminum hydride; triphenylphosphine in toluene T=160 - 270°C; 16 h;
参考文献
Ball, Peter; Fuellmann, Heinz; Heitz, Walter
Angewandte Chemie, 1980 , vol. 92, # 9 p. 742 - 743
反应条件
T=100 - 120°C; P=30753.1 Torr; 4 h; Large scale;
参考文献
Asahi Kasei Chemicals Corporation
Patent: EP1760085 A1, 2007 ;
Location in patent: Page/Page column 43 ;
反应条件
triphenylphosphine; urea
参考文献
Bayer Aktiengesellschaft
Patent: US4327035 A1, 1982 ;
反应条件
di(n-butyl)tin oxide T=140°C; 26 h;
参考文献
Kenar, James A.; Knothe, Gerhard; Copes, Ashley L.
JAOCS, Journal of the American Oil Chemists' Society, 2004 , vol. 81, # 3 p. 285 - 291
反应条件
T=120°C; P=30003 Torr; 3.16667 h; Product distribution / selectivity;
参考文献
Asahi Kasei Chemicals Corporation
Patent: EP1535896 A1, 2005 ;
Location in patent: Page/Page column 29 ;
反应条件
T=120°C; P=30003 Torr; 3.16667 h; Product distribution / selectivity;
参考文献
Asahi Kasei Chemicals Corporation
Patent: EP1535896 A1, 2005 ;
Location in patent: Page/Page column 29 ;
