5-Alpha-二氢可的松合成路线 （共 11 条）
反应条件
foie de boeuf; levure de boulanger; tampon phosphate in water T=37°C; 144 h; Clostridium paraputrificum ATCC No. 25780;
参考文献
Fauve, A.; Kergomard, A.
Tetrahedron, 1981 , vol. 37, p. 899 - 901
参考文献
Kritchevsky et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 483,485
反应条件
pyridine; osmium(VIII) oxide; benzene Behandeln des Reaktionsgemisches mit wss.Na2SO3;
参考文献
Sarett
Journal of the American Chemical Society, 1948 , vol. 70, p. 1454,1455
Journal of the American Chemical Society, 1949 , vol. 71, p. 1169
反应条件
1: dioxane; bromine 2: aq.-ethanolic NaOH 3: N-bromo-acetamide View Scheme
参考文献
Kritchevsky et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 483,485
反应条件
1: aq.-ethanolic NaOH 2: N-bromo-acetamide View Scheme
参考文献
Kritchevsky et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 483,485
反应条件
1: peroxybenzoic acid; benzene / Behandeln des Reaktionsprodukts mit wss.-aethanol.NaOH 2: dioxane; bromine 3: aq.-ethanolic NaOH 4: N-bromo-acetamide View Scheme
参考文献
Kritchevsky et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 483,485
参考文献
Sondheimer et al.
Journal of Organic Chemistry, 1957 , vol. 22, p. 1090
反应条件
Behandeln des Reaktionsgemisches mit Natriumsulfit;
参考文献
Sarett
Journal of the American Chemical Society, 1948 , vol. 70, p. 1454,1455
Journal of the American Chemical Society, 1949 , vol. 71, p. 1169
Full Text Show Details
Graber; Wendler
Journal of the American Chemical Society, 1954 , vol. 76, p. 4474
反应条件
1: toluene-4-sulfonic acid-hydrate 2: sodium borate; aqueous methanol 3: aqueous methanol.H2SO4 View Scheme
参考文献
Evans et al.
Journal of the Chemical Society, 1958 , p. 1529,1536
反应条件
1: toluene-4-sulfonic acid-hydrate 2: sodium borate; aqueous methanol 3: aqueous methanol.H2SO4 4: Acetylierung View Scheme
参考文献
Evans et al.
Journal of the Chemical Society, 1958 , p. 1529,1536
