in methanol formation under exclusion of air and moisture by slow addn. of a methanolic SnBr2 soln. to a methanolic NaOCH3 soln.;; washing with CH3OH; drying in high vac. at 20°C;;
参考文献
Amberger; Kula
Angewandte Chemie, 1963 , vol. 75, p. 476
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Amberger, E.; Kula, M.-R.
Chemische Berichte, 1963 , vol. 96, p. 2562 - 2565
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Gmelin Handbook: Sn: MVol.C1, 3.14.1.1, page 140 - 140
in methanol byproducts: (C2H5)3SnCl; pptn. at dropwise addn. of a soln. of SnCl2 in CH3OH in an inert atmosphere (N2 or Ar) to a soln. of (C2H5)3SnOCH3 in CH3OH under stirring;; washing with CH3OH; drying in vac.;;
参考文献
Mel'nichenko, L. S.; Zemlyanskii, N. N.; Kocheshkov, K. A.
Doklady Akademii Nauk SSSR, 1971 , vol. 200, p. 126 - 127
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Gmelin Handbook: Sn: MVol.C1, 3.14.1.1, page 140 - 140
in methanol; benzene byproducts: Na(CH3C(O)CHC(O)CH3); N2 atmosphere; addn. of soln. of Sn(acac)2 in C6H6 to soln. of Na in MeOH (Sn : Na = 1 : 2, stirring, room temp.), stirring (0.5 h; pptn.); filtration, washing (MeOH, benzene), drying (vac.); elem. anal.;
参考文献
Wakeshima, Ikuko; Suzuki, Toshitaka; Takemoto, Akihiko; Kijima, Ichiro
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1997 , vol. 27, # 5 p. 787 - 796
in methanol; benzene byproducts: Na(CH3OC(O)CHC(O)CH3); N2 atmosphere; addn. of soln. of Sn(mtac)2 in C6H6 to soln. of Na in MeOH (Sn : Na = 1 : 2, stirring, room temp.), stirring (0.5 h; pptn.); filtration, washing (MeOH, benzene), drying (vac.); elem. anal.;
参考文献
Wakeshima, Ikuko; Suzuki, Toshitaka; Takemoto, Akihiko; Kijima, Ichiro
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1997 , vol. 27, # 5 p. 787 - 796
in methanol; benzene byproducts: Na(C2H5OC(O)CHC(O)CH3); N2 atmosphere; addn. of soln. of Sn(etac)2 in C6H6 to soln. of Na in MeOH (Sn : Na = 1 : 2, stirring, room temp.), stirring (0.5 h; pptn.); filtration, washing (MeOH, benzene), drying (vac.); elem. anal.;
参考文献
Wakeshima, Ikuko; Suzuki, Toshitaka; Takemoto, Akihiko; Kijima, Ichiro
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1997 , vol. 27, # 5 p. 787 - 796
in ethylene glycol dimethyl ether reaction with acetic acid in a suspn. of 1.2-dimethoxyethane under formation of tin(II)-acetate;;
参考文献
Morrison, J. S.; Haendler, H. M.
Journal of Inorganic and Nuclear Chemistry, 1967 , vol. 29, p. 393 - 400
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Gmelin Handbook: Sn: MVol.C1, 3.14.1.1, page 140 - 140
