copper(l) iodide; caesium carbonate in N,N-dimethyl-formamide T=135°C; 24 h; Inert atmosphereSealed tube;

sodium tris(acetoxy)borohydride; acetic acid in 1,2-dichloro-ethane T=20°C; 27 h;

暂无反应条件数据

1: molecular sieves 4 Angstroem 2: NaBH4 / methanol / 1 h / 0 °C View Scheme

1.1: methyllithium / tetrahydrofuran; diethyl ether; pentane / 20 h / 0 - 20 °C / |Inert atmosphere 1.2: 1 h / 20 °C / |Inert atmosphere 2.1: ruthenium(II)-carbonyl-tris(triphenylphosphine) dihydride / para-xylene / 24 h / 140 °C / |Schlenk technique; |Glovebox; |Inert atmosphere View Scheme

1.1: methyllithium / tetrahydrofuran; diethyl ether; pentane / 20 h / 0 - 20 °C / |Inert atmosphere 1.2: 1 h / 20 °C / |Inert atmosphere 2.1: ruthenium(II)-carbonyl-tris(triphenylphosphine) dihydride / para-xylene / 24 h / 140 °C / |Schlenk technique; |Glovebox; |Inert atmosphere View Scheme

1.1: methyllithium / tetrahydrofuran; diethyl ether; pentane / 20 h / 0 - 20 °C / |Inert atmosphere 1.2: 1 h / 20 °C / |Inert atmosphere 2.1: ruthenium(II)-carbonyl-tris(triphenylphosphine) dihydride / para-xylene / 24 h / 140 °C / |Schlenk technique; |Glovebox; |Inert atmosphere View Scheme