HClO4; NaClO4 in sodium hydroxide; perchloric acid Kinetics; byproducts: NO3(1-); aq. NaOH; aq. HClO4; at const. ionic strength of 0.75 M (NaClO4 and HClO4) and 25°C; detected by UV spectroscopy;
参考文献
Merenyl, Gabor; Lind, Johan; Czapski, Gideon; Goldstein, Sara
Inorganic Chemistry, 2003 , vol. 42, # 12 p. 3796 - 3800
phosphate buffer; Nitrite in water
Kinetics; byproducts: H(1+); decompd. at 19.5°C in phosphate buffer (pH 4.5) at 0-100 MPa in presence of nitrite; monitored spectrophotometrically;
sodium hydroxide in water
Kinetics; mixing peroxynitrite (0.01 M NaOH) with NaI (0.2 M phosphate buffer at pH 5.8 and at pH 3.2); absorbance at 350 nm;
参考文献
Kurz, Christophe; Zeng, Xiuqiong; Hannemann, Stefan; Kissner, Reinhard; Koppenol, Willem H.
Journal of Physical Chemistry A, 2005 , vol. 109, # 6 p. 965 - 969