(R)-苄氧甲基环氧乙烷合成路线 （共 39 条）
反应条件
C76H94Co2N4O12S2; water in acetonitrile T=20°C; 54 h; optical yield given as percent ee;
参考文献
Dalton Transactions, , vol. 39, # 2 p. 593 - 602
反应条件
1: in chloroform T=0°C; 0.5 h; 2: With potassium carbonate in methanol T=0°C; 0.333333 h; Further stages.;
参考文献
Guindon; Soucy; Yoakim; Ogilvie; Plamondon
Journal of Organic Chemistry, 2001 , vol. 66, # 26 p. 8992 - 8996
反应条件
1: 3N HCl / 65 °C 2: PPh3, diethylazodicarboxylate / tetrahydrofuran / Heating View Scheme
参考文献
Farmaco, Edizione Scientifica, , vol. 43, # 12 SUPPL. p. 1153 - 1163
反应条件
1: 93 percent / molecular sieves 3 Angstroem / BF3*Et2O / CH2Cl2 / 1.) O deg C, 12 h; 2.) 20 deg C, 2 h 2: 98 percent / K2CO3 / methanol / 1.) -10 deg C, 2 h; 2.) r.t., 2 h View Scheme
参考文献
Tetrahedron Letters, , vol. 30, # 21 p. 2751 - 2754
反应条件
Pseudomonas oleovorans monooxygenase (POM); Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 113, # 15 p. 5878 - 5880
反应条件
1: 94 percent / 30percent NaOH / tributylbenzylammonium chloride / 4 h / 50 °C 2: 91 percent / 1N H2SO4 / 1 h / 90 °C 3: 64.5 percent / pyridine / CHCl3 / Ambient temperature 4: 70 percent / t-BuOK / tetrahydrofuran / 0.33 h / Ambient temperature View Scheme
参考文献
Helvetica Chimica Acta, , vol. 65, # 3 p. 1059 - 1084
反应条件
sodium hydride in N,N-dimethyl-formamide T=20°C;
参考文献
Bioorganic and Medicinal Chemistry Letters, , vol. 20, # 12 p. 3809 - 3813
反应条件
sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate 1.) 0 deg C, 30 min, 2.) RT, 4 h;
参考文献
Partali; Waagen; Alvik; Anthonsen
Tetrahedron Asymmetry, 1993 , vol. 4, # 5 p. 961 - 968
反应条件
potassium carbonate in hexane T=25°C; 1 h;
参考文献
Shaikh, Tanveer Mahamadali; Sudalai, Arumugam
Tetrahedron Asymmetry, 2009 , vol. 20, # 19 p. 2287 - 2292
反应条件
Bacillus megaterium ECU1001 epoxide hydrolase in potassium phosphate buffer; dimethyl sulfoxide T=30°C; pH=7; 2 h; Resolution of racemateEnzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Advanced Synthesis and Catalysis, , vol. 353, # 9 p. 1510 - 1518
