5,6,11,12-四氢二苯并[a,e]环辛烯合成路线 （共 46 条）
反应条件
1: NBS 2: (i) collidine, DMSO, (ii) H2O View Scheme
参考文献
Yates,P. et al.
Canadian Journal of Chemistry, 1970 , vol. 48, p. 788 - 795
反应条件
1: NBS 2: (i) collidine, DMSO, (ii) H2O View Scheme
参考文献
Yates,P. et al.
Canadian Journal of Chemistry, 1970 , vol. 48, p. 788 - 795
反应条件
lithium
1 h; Irradiation;
参考文献
Hamza, Abdulhamid
Structural Chemistry, 2010 , vol. 21, # 4 p. 787 - 793
反应条件
N,N,1,1,1-pentamethylsilanecarboxamide; tetrakis(triphenylphosphine) palladium(0) in toluene
T=100°C; 11 h;
参考文献
Cunico, Robert F.; Pandey, Rajesh K.
Journal of Organic Chemistry, 2005 , vol. 70, # 22 p. 9048 - 9050
反应条件
ethanol; platinum
P=117681 Torr; Hydrogenation;
参考文献
Fieser; Pechet
Journal of the American Chemical Society, 1946 , vol. 68, p. 2577,2579
反应条件
1: KOtBu / tetrahydrofuran
2: H2 / Pt
3: Br2 / Irradiation
4: KOtBu / tetrahydrofuran
5: H2 / Pt
View Scheme
参考文献
Wong,H.N.C. et al.
Journal of the American Chemical Society, 1974 , vol. 96, # 17 p. 5604 - 5605
反应条件
1: H2 / Pt
2: Br2 / Irradiation
3: KOtBu / tetrahydrofuran
4: H2 / Pt
View Scheme
参考文献
Wong,H.N.C. et al.
Journal of the American Chemical Society, 1974 , vol. 96, # 17 p. 5604 - 5605
反应条件
lithium in tetrahydrofuran
T=65 - 70°C; 2 h; Inert atmosphere;
参考文献
Franck, Geraldine; Brill, Marcel; Helmchen, Guenter
Organic Syntheses, 2012 , vol. 89, p. 55 - 65
反应条件
potassium fluoride; (η3-allyl)(η5-Cp)Pd in N,N-dimethyl-formamide
T=100°C; 3 h;
参考文献
Ueno, Satoshi; Ohtsubo, Masakazu; Kuwano, Ryoichi
Journal of the American Chemical Society, 2009 , vol. 131, # 36 p. 12904 - 12905
反应条件
naphthalene; lithium in tetrahydrofuran
T=-78 - 20°C; 5 h;
参考文献
Guijarro, D.; Mancheno, B.; Yus, M.
Tetrahedron, 1992 , vol. 48, # 22 p. 4593 - 4600
