lithium aluminium tetrahydride in diethyl ether Ge compd. soln. added to excess of LiAlH4 in Et2O, refluxed for 2 h; hydrolyzed, extd. (Et2O), dried (Na2SO4), distd.;
参考文献
Escudie, Jean; Couret, Claude; Satge, Jacques; Andriamizaka, Jean Dominique
Organometallics, 1982 , vol. 1, p. 1261 - 1265
Audett, Judy A. nee Christie; Mackay, Kenneth M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 2635 - 2644
in pentane under N2, shaken for 15 min; prolonged pumping through cooled traps, GeMe2H2 not isolated;
参考文献
Audett, Judy A. nee Christie; Mackay, Kenneth M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 2635 - 2644
Audett, Judy A. nee Christie; Mackay, Kenneth M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 2635 - 2644
CCl4 in benzene under N2, 1 or 2 days; ratio educt: GeMe2H2 : GeMe2HCl : ((Fe(CO)4(GeH3))2GeMe2) : ((Fe(CO)4)2(GeCl2)(GeH2)) after 1 day 86:5:4:3:2, after 2 days 65:8:15:3:9;
参考文献
Audett, Judy A. nee Christie; Mackay, Kenneth M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 2635 - 2644
CCl4 in benzene under N2, 5 days, further product GeH4; ratio educt: GeMe2H2 : GeMe2HCl : ((Fe(CO)4(GeH3))2GeMe2) : ((Fe(CO)4)2(GeCl2)(GeH2)) :((Fe(CO)4(GeH2)2): GeH4 after 5 day 30:11:36:3:15:2:2;
参考文献
Audett, Judy A. nee Christie; Mackay, Kenneth M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 2635 - 2644
