Audett, Judy A. nee Christie; Mackay, Kenneth M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 2635 - 2644
in hexane
under N2, reaction time: 10 min; removal of volatiles;
参考文献
Audett, Judy A. nee Christie; Mackay, Kenneth M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 2635 - 2644
in cyclohexane
Irradiation (UV/VIS); photolysis (185 nm); 14percent conversion; react. mechanism discussed; 39percent Me3GeH, 33percent Me4Ge, and 23percent (Me3Ge)2GeMe2 obtained;
参考文献
Nakadaira, Yasuhiro; Zhou, Da-Yang; Kako, Masahiro; Mochida, Kunio
Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan), 1994 , p. 253 - 257
in methanol
a mixt. of Me3GeSnMe3 and Me2SnCl2 in methanol was kept for 7 h, reaction was followed by (1)H NMR spectroscopy; most of the reactants have been consumed, Me3GeSnMe2Cl and Me2SnHCl were not found, "dimethyltin polymer" was also present; not isolated, identified by (1)H NMR spectrum;
参考文献
Cuthberston, Matthew J.; Wells, Peter R.
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 25 - 38
in methanol
Kinetics; byproducts: Me(CD3)2SnCl; a mixt. of Me3GeSnMe3 and (CD3)3SnCl in methanol was kept for 220 min, reaction was followed by (1)H NMR spectroscopy; no Me2SnHCl, Me2SnCl2, and "dimethyltin polymer" were observed; first order behaviour up to 60percent reaction, rate const. is given; not isolated, identified by (1)H and (2)H NMR spectra;
参考文献
Cuthberston, Matthew J.; Wells, Peter R.
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 25 - 38
Nakadaira, Yasuhiro; Zhou, Da-Yang; Kako, Masahiro; Mochida, Kunio
Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan), 1994 , p. 253 - 257
in cyclohexane
Irradiation (UV/VIS); photolysis (185 nm); react. mechanism discussed;
参考文献
Nakadaira, Yasuhiro; Zhou, Da-Yang; Kako, Masahiro; Mochida, Kunio
Nippon Kagaku Kaishi (Journal of the Chemical Society of Japan), 1994 , p. 253 - 257
