Brinkman, Elizabeth A.; Salomon, Karen; Tumas, William; Brauman, John I.
Journal of the American Chemical Society, 1995 , vol. 117, # 17 p. 4905 - 4910
Brinkman, Elizabeth A.; Salomon, Karen; Tumas, William; Brauman, John I.
Journal of the American Chemical Society, 1995 , vol. 117, # 17 p. 4905 - 4910
in cyclohexane
Irradiation (UV/VIS); irradiation of catenate in cyclohexane containing a large excess of 2,3-dimethylbutadiene as trapping agent with a 110 W low pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;
参考文献
Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro
Journal of Organometallic Chemistry, 1991 , vol. 412, # 1.2 p. 9 - 19
methanol in benzene
Irradiation (UV/VIS); irradiation of catenate in benzene containing an excess of methanol with a 110 W low pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;
参考文献
Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro
Journal of Organometallic Chemistry, 1991 , vol. 412, # 1.2 p. 9 - 19
in cyclohexane
Irradiation (UV/VIS); irradiation of catenate in cyclohexane with a 110 W low pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;
参考文献
Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro
Journal of Organometallic Chemistry, 1991 , vol. 412, # 1.2 p. 9 - 19
Audett, Judy A. nee Christie; Mackay, Kenneth M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 2635 - 2644
in further solvent(s)
(Ar); Ge-compound added to a suspn. of LiAlH4 in ethyl ether; stirred for 12-72 h at room temp.; decanted; added water; washed with water; dried; filtered; evapd.; distd.;
参考文献
Clark, K. Brady; Griller, David
Organometallics, 1991 , vol. 10, p. 746 - 750
hydrogenchloride in methanol
Kinetics; 8.5 M aq. HCl was added to a methanol soln. of the stannane in a NMR tube, reaction was followed by (1)H NMR spectroscopy for 50 h; 70percent of the substrate has been consumed, rate consts. according to different reaction paths are given; further products; not isolated, identified by (1)H NMR spectrum;
参考文献
Cuthberston, Matthew J.; Hawker, Darryl W.; Wells, Peter R.
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 7 - 24
in gas
byproducts: ethane, methane, ethene; Irradiation (UV/VIS); photolysis by an ArF laser (193.3nm); glass reactor, detailed description given; react. mechanism discussed; photolytic pathways described;; monitoring the progress of photolysis directly in the reactor by use of an FTIR spectrometer; final amt. of methane, ethene and ethane were determined by gas-chromatography;;
参考文献
Pola, Josef; Taylor, Roger
Journal of Organometallic Chemistry, 1992 , vol. 437, # 3 p. 271 - 278
