7-酮基去氢表雄酮醋酸酯合成路线 （共 22 条）
反应条件
2-hydroxy-1,3-isoindolinedione; sodium dichromate; chromium(III) perchlorate in water; acetonitrile T=20°C; 48 h; Product distribution / selectivity;
参考文献
Humanetics Corporation
Patent: US6384251 B1, 2002 ;
Location in patent: Page column 7-8 ;
反应条件
tert.-butylhydroperoxide; copper(l) iodide in decane; acetonitrile T=50°C; 24 h; Title compound not separated from byproducts;
参考文献
Salvador; Clark
Chemical Communications, 2001 , # 1 p. 33 - 34
反应条件
chromyl acetate in dichloromethane T=-78°C; 0.25 h;
参考文献
Journal of Chemical Research, Miniprint, , # 12 p. 3245 - 3260
反应条件
tert.-butylhydroperoxide; sodium hydroxide; sodium acetate; sodium sulfite in water; acetic anhydride; ethyl acetate
反应条件
tert.-butylhydroperoxide; chromium(VI) oxide in dichloromethane 24 h; Ambient temperature;
参考文献
Tetrahedron Letters, , vol. 28, # 40 p. 4665 - 4668
反应条件
C28H38F6MnN4O8S2; dihydrogen peroxide; 2-oxo-3,3-dimethyl-butanoic acid in water; ethyl acetate; acetonitrile T=20°C; 1 h; Reagent/catalyst; diastereoselective reaction;
参考文献
Cusso, Olaf; Garcia-Bosch, Isaac; Font, David; Ribas, Xavi; Lloret-Fillol, Julio; Costas, Miquel
Organic Letters, 2013 , vol. 15, # 24 p. 6158 - 6161
反应条件
chromium(VI) oxide in acetic anhydride; acetic acid T=90 - 95°C; 1 h;
参考文献
Miljkovic, Dusan; Gasi, Katarina; Kindjer, Marija; Stankovic, Slobodanka; Argay, Gyula
Tetrahedron, 1987 , vol. 43, # 3 p. 631 - 641
反应条件
chromium(VI) oxide in water; acetic acid T=90 - 95°C; 1 h;
参考文献
Tetrahedron, , vol. 43, # 3 p. 631 - 641
反应条件
ferric picolinate complexes; dihydrogen peroxide in acetonitrile 3 h; Ambient temperature;
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 45, # 4 p. 750 - 752
反应条件
toluene-4-sulfonic acid 0.0333333 h; microwave irradiation;
参考文献
Marwah, Padma; Marwah, Ashok; Lardy, Henry A.
Tetrahedron, 2003 , vol. 59, # 13 p. 2273 - 2287
