(S)-(-)-2-lt;2',2'-dimethyl-1'-(2''-pyridyl)propoxygt;-1,1-di-(α-naphthyl)ethanol in hexane 4 h; Ambient temperatureother aldehydes, other dialkylzinc, var. chiral alcohols as ligands, var. reaction time; Product distributionMechanism;
Choi, Jun Ho; Choi, Yoon Kyung; Kim, Yu Hwan; Park, Eun Sil; Kim, Eun Jung; Kim, Mahn-Joo; Park, Jaiwook
Journal of Organic Chemistry, 2004 , vol. 69, # 6 p. 1972 - 1977
1: With sodium borodeuteride in methanol T=0°C; 2 h; 2: With n-tetradec-1l-ene; oxygen; (-)-sparteine; palladium diacetate in 1,2-dichloro-ethane 72 h; Further stages. Title compound not separated from byproducts.;
参考文献
Journal of the American Chemical Society, , vol. 124, # 28 p. 8202 - 8203