(1S,3R,4S,5R,7R)-N-hydroxy-4-benzyl-1-isopropyl-2-azaadamantane; sodium hydrogencarbonate in dichloromethane T=-40°C; 3 h; Resolution of racemateInert atmosphere; optical yield given as percent eeenantioselective reaction;
N-heterocyclic carbene-palladacycle; sodium t-butanolate in tetrahydrofuran T=70°C; 0.5 h;
参考文献
Navarro, Oscar; Marion, Nicolas; Oonishi, Yoshihiro; Kelly III, Roy A.; Nolan, Steven P.
Journal of Organic Chemistry, 2006 , vol. 71, # 2 p. 685 - 692
N-heterocyclic carbene-palladacycle; sodium t-butanolate in tetrahydrofuran T=70°C; 1 h;
参考文献
Navarro, Oscar; Marion, Nicolas; Oonishi, Yoshihiro; Kelly III, Roy A.; Nolan, Steven P.
Journal of Organic Chemistry, 2006 , vol. 71, # 2 p. 685 - 692
