2,6-双(对-甲基苯)吡啶合成路线 （共 17 条）
反应条件
chloro(1,3-bis(pyridin-2-ylmethyl)imidazolylidene)nickel(II) hexafluorophosphate in tetrahydrofuran T=20°C; Kumada-Corriu coupling reaction; 12 h; Inert atmosphere;
参考文献
Chen, Chao; Qiu, Huayu; Chen, Wanzhi
Journal of Organometallic Chemistry, 2012 , vol. 696, # 26 p. 4166 - 4172
反应条件
1: Cp2TiCl2 With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; 2: hex-3-yne in tetrahydrofuran; hexane T=-10°C; 3 h; 3: 4-cyanotoluene in tetrahydrofuran; hexane 1 h; Heating;
参考文献
Journal of the American Chemical Society, , vol. 125, # 32 p. 9568 - 9569
反应条件
C21H18N8Ni2O(2+)*2F6P(1-) in tetrahydrofuran; 1-methyl-pyrrolidin-2-one T=20 - 80°C; Negishi coupling reaction;
参考文献
Xi, Zhenxing; Zhou, Yongbo; Chen, Wanzhi
Journal of Organic Chemistry, 2008 , vol. 73, # 21 p. 8497 - 8501
反应条件
C16H16Cl2CoN8(1+)*F6P(1-) in tetrahydrofuran T=20°C; Kumada-Corriu cross-coupling; 2 h;
参考文献
Xi, Zhenxing; Liu, Bin; Lu, Chunxin; Chen, Wanzhi
Dalton Transactions, 2009 , # 35 p. 7008 - 7014
反应条件
C68H72Cl2N6NiP2 in tetrahydrofuran T=25°C; 24 h; Inert atmosphere;
参考文献
Xie, Lan-Gui; Wang, Zhong-Xia
Chemistry - A European Journal, 2011 , vol. 17, # 18 p. 4972 - 4975
反应条件
[Pd(Cl)κ2-S,N-C6H4CS=N-(4-Py)(PPh3)]; potassium carbonate in toluene T=80°C; Suzuki coupling; 5 h;
参考文献
Sindhuja, Elangovan; Ramesh, Rengan; Liu, Yu
Dalton Transactions, 2012 , vol. 41, # 17 p. 5351 - 5361
反应条件
hafnium triflate; ammonium acetate in toluene T=100°C; 1 h; Inert atmospheresealed vial;
参考文献
Sasada, Toshiaki; Kobayashi, Fuminori; Moriuchi, Masato; Sakai, Norio; Konakahara, Takeo
Synlett, 2011 , # 14 art. no. U00211ST, p. 2029 - 2034
反应条件
dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; palladium diacetate; potassium hydroxide in neat (no solvent) T=110°C; Suzuki-Miyaura Coupling; 24 h; Schlenk techniqueInert atmosphere;
参考文献
Asachenko, Andrey F.; Sorochkina, Kristina R.; Dzhevakov, Pavel B.; Topchiy, Maxim A.; Nechaev, Mikhail S.
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 18 p. 3553 - 3557
反应条件
potassium tert-butylate in ethylene glycol dimethyl ether T=0°C; 1.5 h;
参考文献
Quast, Helmut; Mueller, Bodo
Chemische Berichte, 1983 , vol. 116, # 12 p. 3931 - 3946
反应条件
C35H50I2N2O2PPd; caesium carbonate in 1,4-dioxane T=110°C; Suzuki Coupling; 12 h; Inert atmosphere;
参考文献
Xu, Chen; Hao, Xin-Qi; Li, Zhen; Duan, Lu-Meng; Wang, Zhi-Qiang; Ji, Bao-Ming; Song, Mao-Ping
Bulletin of the Korean Chemical Society, 2012 , vol. 33, # 10 p. 3430 - 3432
