3,3,5,5-四甲基环己酮合成路线 （共 36 条）
反应条件
1: methyl-magnesium chloride With copper(I) bromide dimethylsulfide complex; formaldehyde diethyl acetal in tetrahydrofuran T=0 - 20°C; 0.25 h; 2: 3,5,5-trimethyl-cyclohex-2-en-1-one in tetrahydrofuran T=0 - 20°C; 0.5 h;
参考文献
Boaz, Neil W.; Venepalli, Bhaskar
Organic Process Research and Development, 2001 , vol. 5, # 2 p. 127 - 131
反应条件
Envirocat EPZG in water; acetone T=80°C; 4 h;
参考文献
Ballini, Roberto; Bosica, Giovanna; Maggi, Raimondo; Sartori, Giovanni
Synlett, 1997 , vol. 1997, # 7 p. 795 - 796
反应条件
copper(I) iodide-lithium chloride in tetrahydrofuran T=0°C; 0.5 h;
参考文献
Reetz, Manfred T.; Kindler, Alois
Journal of Organometallic Chemistry, 1995 , vol. 502, # 1-2 p. C5 - C7
反应条件
chloro-trimethyl-silane; copper(I) bromide in tetrahydrofuran; hexane 4 h;
参考文献
Kabbara, Jazid; Flemming, Steffen; Nickisch, Klaus; Neh, Harribert; Westermann, Juergen
Tetrahedron Letters, 1994 , vol. 35, # 46 p. 8591 - 8594
反应条件
N,N'-dimethyl-N,N'-propyleneurea; samarium diiodide in tetrahydrofuran T=-78 - 20°C; 0.0833333 h;
参考文献
Batey, Robert A.; Harling, John D.; Motherwell, William B.
Tetrahedron, 1996 , vol. 52, # 35 p. 11421 - 11444
反应条件
in diethyl ether T=0°C; 1 h;
参考文献
Piers, Edward; Cheng, Kin Fai; Nagakura, Isao
Canadian Journal of Chemistry, 1982 , vol. 60, p. 1256 - 1263
反应条件
in diethyl ether T=0°C; 1 h;
参考文献
Piers, Edward; Cheng, Kin Fai; Nagakura, Isao
Canadian Journal of Chemistry, 1982 , vol. 60, p. 1256 - 1263
反应条件
in diethyl ether T=0°C; 1 h;
参考文献
Piers, Edward; Cheng, Kin Fai; Nagakura, Isao
Canadian Journal of Chemistry, 1982 , vol. 60, p. 1256 - 1263
反应条件
diethyl ether; copper(l) chloride
参考文献
Justus Liebigs Annalen der Chemie, , vol. 672, p. 103 - 133
Bulletin des Societes Chimiques Belges, , vol. 63, p. 357,363, 376
Journal of the American Chemical Society, , vol. 63, p. 2308,2313
Journal of the American Chemical Society, , vol. 67, p. 128,130
反应条件
CH2=C(Me)Cu(CN)Li2 in diethyl ether T=-50°C; 3.5 h; Yield given. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 49, # 21 p. 3938 - 3942
