NiBr2*diglyme; (R,R)-C5H3N(C3H3NO(CH(CH3)2))2; KOCH2CH3 in di-isopropyl ether; N,N-dimethyl acetamide reaction of 1:1 mixt. of bromoderivs. with 0.27 equiv. of diboron compd.in presence of nickel compd., pyridine deriv. and 0.25 equiv. of KOEt i n diisopropyl ether/dimethylacetamide at room temp.;

1: 80 percent / Cs2CO3 / dimethylformamide / 10 h / 0 °C 2: 97 percent / Bu3SnH, AIBN / benzene / 1 h / Heating View Scheme

2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene 1.5 h; Heating;

ammonium perchlorate; N(Et)4ClO4; acrylic acid methyl ester; lt;Ni(tet a)gt;(ClO4)2 in N,N-dimethyl-formamide Ambient temperatureelectrolysis: graphite plate cathode; 1.7 F*mol-1;

ammonium perchlorate; N(Et)4ClO4; lt;Ni(tet a)gt;(ClO4)2 in N,N-dimethyl-formamide Ambient temperatureelectrolysis: graphite plate cathode; 1.7 F*mol-1;

1: potassium carbonate / acetone / 4 h / |Reflux; |Inert atmosphere 2: iron (III) acetylacetonate / diethyl ether / 18 h / |Reflux; |Inert atmosphere View Scheme

1.1: triethylamine / dichloromethane / 3 h / 20 °C / Cooling with ice 2.1: oxygen / toluene / 24 h / 100 °C 2.2: 12 h 2.3: pH 12 - 13 View Scheme

暂无反应条件数据

暂无反应条件数据

1.1: potassium carbonate / acetone / 24 h / |Reflux; |Inert atmosphere 2.1: (NH4)6[Mo7O24]*4H2O; dihydrogen peroxide / methanol; water / 2.5 h / 0 - 20 °C / |Inert atmosphere 3.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C / |Inert atmosphere 3.2: 20 h / 20 °C / |Inert atmosphere 4.1: N,N,N',N,-tetramethylethylenediamine; iron (III) acetylacetonate; CPME / diethyl ether / 18 h / 20 °C / |Inert atmosphere View Scheme