反应条件
tetrahydrofuran in tetrahydrofuran byproducts: Re(III) oxide, formate(1-), carbonate(2-); High Pressure; dissolving Re2O7 in THF in autoclave, stirring, inert atmosphere; pressurizing with 13 MPa of CO; heating in oil bath at 150°C for 4 h;; filtration from black solid; concentrating; isolation of (Re(CO)6)(1+) by selective pptn. with cyclohexane from Re(CO)5(THF) containing soln.; detn. by IR and NMR spectroscopy;;
参考文献
Marchionnna, Mario; Lami, Massimo; Raspolli Galletti, Anna Maria; Braca, Guiseppe
Gazzetta Chimica Italiana, 1993 , vol. 123, p. 107 - 110
