acetonitrile in acetonitrile Kinetics; byproducts: Re2(CO)9(MeCN); Irradiation (UV/VIS); Ar-atmosphere; Nd:Yag laser pulses (351 and 355 nm); not isolated, reaction followed by UV/VIS spectroscopy;
acetonitrile in acetonitrile Kinetics; byproducts: Re2(CO)9(MeCN); Irradiation (UV/VIS); Ar-atmosphere; Nd:Yag laser pulses (351 and 355 nm); not isolated, reaction followed by UV/VIS spectroscopy;
acetonitrile in acetonitrile Kinetics; byproducts: Re2(CO)9(MeCN); Irradiation (UV/VIS); Ar-atmosphere; Nd:Yag laser pulses (351 and 355 nm); not isolated, reaction followed by UV/VIS spectroscopy;
in cyclohexane A soln. of Re2(CO)10 is treated with Br2 at room temp.;
参考文献
Wu, Guanmin; Glass, David R.; May, Daniel; Watson, William H.; Wiedenfeld, David; Richmond, Michael G.
Journal of Organometallic Chemistry, 2005 , vol. 690, # 21-22 p. 4993 - 4999
in neat (no solvent) (Ar); using Schlenk techniques; heating of 0.8 mmol of 6,6-dimethylfulvene with 0.2 mmol of Re2(CO)10 at 155°C for 2 h; filtration on silica gel (petroleum ether-CH2Cl2, 95:5), as oil;
参考文献
Le Bideau; Henique; Pigeon; Joerger; Top; Jaouen
Journal of Organometallic Chemistry, 2003 , vol. 668, # 1-2 p. 140 - 144
