in acetonitrile Kinetics; react. of the metal carbonyl anion (0.001 M) with an excess of the Co(III) complex (0.10-0.30 M) at 25°C in CH3CN;; detn. by decrease of the IR intensity of the metal carbonyl anion;;
in neat (no solvent) under N2, Re-compelx was evacuated, heated in 94-95°C oil bath, cooled, 1 equiv of Ph3SnCl in THF was added, stirred for 1 h; detected by silica gel TLC;
参考文献
Tam, Wilson; Marsi, Marianne; Gladisz, J. A.
Inorganic Chemistry, 1983 , vol. 22, p. 1413 - 1421
in tetrahydrofuran byproducts: (CF3)3CCF=CFH; under Ar; react. of (Re(CO)5)Na with (Z)-(CF3)3CCF=CFCl in the presence of t-BuOH (10 equiv) in THF at room temp.; not isolated; IR, NMR;
参考文献
Journal of Organometallic Chemistry, , vol. 681, # 1-2 p. 59 - 69
