2-[3-(三氟甲基)苯基]环氧乙烷合成路线 （共 4 条）
反应条件
sodium hydride in dimethyl sulfoxide T=20°C;
参考文献
Deregnaucourt, Justine; Archelas, Alain; Barbirato, Fabien; Paris, Jean-Marc; Furstoss, Roland
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 8-9 p. 1405 - 1417
反应条件
[bis(acetoxy)iodo]benzene; water in dichloromethane T=25°C; 48 h; chemoselective reaction;
参考文献
Vaquer, Lydia; Riente, Paola; Sala, Xavier; Jansat, Susanna; Benet-Buchholz, Jordi; Llobet, Antoni; Pericas, Miquel A.
Catalysis Science and Technology, 2013 , vol. 3, # 3 p. 706 - 714
反应条件
hexafluoroisopropyl alcohol; hydroxy(phenyl)(tetrafluoroborato)-λ3-iodane in dichloromethane; water T=20°C; 6 h;
参考文献
Miyamoto, Kazunori; Tada, Norihiro; Ochiai, Masahito
Journal of the American Chemical Society, 2007 , vol. 129, # 10 p. 2772 - 2773
反应条件
1: 69 percent Spectr. / hydroxy(phenyl)(tetrafluoroborato)-λ3-iodane; 1,1,1,3,3,3-hexafluoro-2-propanol / CH2Cl2; H2O / 6 h / 20 °C 2: NaBH4 / methanol / 1 h / 20 °C View Scheme
参考文献
Miyamoto, Kazunori; Tada, Norihiro; Ochiai, Masahito
Journal of the American Chemical Society, 2007 , vol. 129, # 10 p. 2772 - 2773
