NaOH in water-d2 Kinetics; Co complex dissolved in D2O contg. 0.1 M disodium ethylenediaminetetraacetate, pH adjusted to 7.4 with 1.0 M NaOH, kept at room temp. for 34 days; NMR anal.;
参考文献
Journal of the American Chemical Society, , vol. 106, # 10 p. 2812 - 2818
P4 in water byproducts: hypophosphate, triphosphate, tetraphosphate; phosphorus dissolved in CS2; further byproduct: MnO2-hydrate; detn. of products by paper chromatography;
dimethylsulfide; sodium perchlorate in water Kinetics; byproducts: (CH3)2SO; Me2S oxidized by peroxomonophosphoric acid in aq. medium at 298-313 K, pH 12.72-13.70, ionic strength 0.4-0.55 mol/dm**3 (NaClO4);
参考文献
Bulletin of the Chemical Society of Japan, , vol. 53, # 8 p. 2366 - 2370
