(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
in 1,2-dichloro-ethane T=150°C; 5 h; Inert atmosphereSealed tubeSchlenk technique;
参考文献
Organometallics, , vol. 33, # 6 p. 1328 - 1332
反应条件
in 1,2-dichloro-ethane T=150°C; 9 h; Inert atmosphereSealed tubeSchlenk technique;
参考文献
Organometallics, , vol. 33, # 6 p. 1328 - 1332
反应条件
in 1,2-dichloro-ethane T=150°C; 5 h; Inert atmosphereSealed tubeSchlenk technique;
参考文献
Organometallics, , vol. 33, # 6 p. 1328 - 1332
反应条件
in methanol; dichloromethane N2, equimol., a soln. of gold compd. (methanol) added to a soln. of phosphane (CH2Cl2), stirred for 2 h; concd., pptd. (water), ppt. filtered, washed (water), dried (vac.);
参考文献
Olkowska-Oetzel, Jolanta; Sevillano, Paloma; Eichhoefer, Andreas; Fenske, Dieter
European Journal of Inorganic Chemistry, 2004 , # 5 p. 1100 - 1106
反应条件
in toluene byproducts: SEt2; (N2); using Schlenk techniques; addn. of PdCl2(SEt2)2 (1 equiv.) to soln. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) in toluene; stirring for 30 minat room temp.; concn., addn. of Et2O, pptn., concn. of soln., addn. of pentane, pptn., elem. anal.;
参考文献
Organometallics, , vol. 21, # 21 p. 4556 - 4559
反应条件
in benzene byproducts: PPh3; (N2); using Schlenk techniques; addn. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) to soln. of NiCl2(PPh3)2 (1 equiv.) in benzene; stirring for 30 minat room temp.; concn., extn. with Et2O, pptn., concn. of soln., elem. anal.;
参考文献
Contel, Maria; Stol, Marianne; Casado, Miguel A.; Van Klink, Gerard P.M.; Ellis, Dianne D.; Spek, Anthony L.; Van Koten, Gerard
Organometallics, 2002 , vol. 21, # 21 p. 4556 - 4559
反应条件
hydrogenchloride in hydrogenchloride addn. of N HCl to soln. of Au-complex, stirring (2 min); solvent removal (vac.), extn. of o-nitrophenol from solid residue by ether; ppt. dissoln. in chloroform, salting out by petroleum ether;
参考文献
Sov. J. Coord. Chem. (Engl. Transl.), , vol. 15, p. 316 - 323
Koordinatsionnaya Khimiya, , vol. 15, p. 504 - 523
反应条件
in toluene byproducts: tht; (N2); using Schlenk techniques; addn. of soln. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) in toluene to soln. of AuCl3(tht) (1 equiv.) in toluene atroom temp.; pptn., sepn., washing with Et2O, drying in vac., evapn. of mother liquorto dryness, pptn., elem. anal.;
参考文献
Organometallics, , vol. 21, # 21 p. 4556 - 4559
反应条件
Cs2CO3 in tetrahydrofuran reaction at room temp.; flash chromy. (silica gel);
参考文献
Seidel, Guenter; Lehmann, Christian W.; Fuerstner, Alois
Angewandte Chemie - International Edition, 2010 , vol. 49, # 45 p. 8466 - 8470
反应条件
in toluene (N2); using Schlenk techniques; addn. of soln. of Au(C6H3(CH2NMe2)2)(PPh3) (1 equiv.) in toluene to soln. of anhyd. FeCl3 (1 equiv.) in degassed, dry toluene; stirring for 5 h at room temp.; removal of solvent in vac., extn. with degassed, dry Et2O, pptn., transferring of soln. to another flask by cannula, concn., cooling at -20°C, crystn.;
参考文献
Contel, Maria; Stol, Marianne; Casado, Miguel A.; Van Klink, Gerard P.M.; Ellis, Dianne D.; Spek, Anthony L.; Van Koten, Gerard
Organometallics, 2002 , vol. 21, # 21 p. 4556 - 4559
