(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
in dichloromethane 18 h;
参考文献
Price, Gregory A.; Brisdon, Alan K.; Flower, Kevin R.; Pritchard, Robin G.; Quayle, Peter
Tetrahedron Letters, 2014 , vol. 55, # 1 p. 151 - 154
反应条件
in 1,2-dichloro-ethane T=150°C; 22 h; Inert atmosphereSchlenk technique;
参考文献
Hofer, Manuel; Nevado, Cristina
Tetrahedron, 2013 , vol. 69, # 27-28 p. 5751 - 5757
反应条件
1: hydrogen tetrachloroaurate(III) tetrahydrate With di-n-propyl sulfide in ethanol T=40°C; 0.166667 h; 2: triphenylphosphine in ethanol T=40°C; 1 h; Reagent/catalystTemperatureTime;
参考文献
Zalesskiy, Sergey S.; Sedykh, Alexander E.; Kashin, Alexey S.; Ananikov, Valentine P.
Journal of the American Chemical Society, 2013 , vol. 135, # 9 p. 3550 - 3559
反应条件
1,2,4-trimethoxy benzene in 1,2-dichloro-ethane T=150°C; 22 h; Inert atmosphereSchlenk technique; Reagent/catalyst;
参考文献
Tetrahedron, , vol. 69, # 27-28 p. 5751 - 5757
反应条件
1: 2,6-di-tert-butylpyridine / not given 2: not given 3: not given View Scheme
参考文献
Angewandte Chemie, International Edition, , vol. 48, p. 5733 - 5736
Angewandte Chemie, , vol. 121, p. 5843 - 5846
反应条件
in acetone Au(mes)(PPh3) added to a soln. of PPN(AuCl4), refluxed for 2 h; cooled at room temp., concd., pptd. (toluene), filtered, washed (toluene), dried (vac.) to give cis-PPN(Au(mes)2Cl2); the toluene filtrate concd., pptd. (cold hexane) to give AuCl(PPh3);
参考文献
Journal of the American Chemical Society, , vol. 125, # 39 p. 11925 - 11935
反应条件
1: alumina / not given 2: not given View Scheme
参考文献
Angewandte Chemie, International Edition, , vol. 48, p. 5733 - 5736
Angewandte Chemie, , vol. 121, p. 5843 - 5846
反应条件
hydrochloric acid in chloroform a soln. of Au-complex in CHCl3 was shaken with conc. HCl for 5 min; org. layer was sepd., washed with an aq. Na2CO3, water, dried over K2CO3, evapd. in vacuo, residue was dissolved in a min. CHCl3, filtered, dild. with hexane; identified by m. p.;
参考文献
Perevalova, E. G.; Bolesov, I. G.; Struchkov, Yu. T.; Leschova, I. F.; Kalyuzhnaya, Ye. S.; et al.
Journal of Organometallic Chemistry, 1985 , vol. 286, p. 129 - 144
反应条件
in dichloromethane byproducts: Me2S; N2-atmosphere; addn. of equimolar amt. of phosphine to Au-complex soln. over 5 min; in air; pptn. on hexane addn., evapn. (reduced pressure), filtration, recrystn. (CH2Cl2/hexane), drying (vac.); elem. anal.;
参考文献
Mueller, Thomas E.; Green, Jennifer C.; Mingos, D. Michael P.; McPartlin, C. Mary; Whittingham, Conrad; Williams, David J.; Woodroffe, Thomas M.
Journal of Organometallic Chemistry, 1998 , vol. 551, # 1-2 p. 313 - 330
反应条件
chloroform in chloroform; benzene chloroform/benzene = 1:1, room temp., 3 h; not isolated, identification by PMR spectroscopy; elem. anal.;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 54, p. 2424 - 2426
Zhurnal Obshchei Khimii, , vol. 54, p. 2711 - 2714
