triethylamine; triphenylphosphine in benzene byproducts: triphenylphosphine oxide; treatment of soln. of Pd-compd. and PPh3 with excess of N(C2H5)3 at 40°C for 2 days;; not isolated; (31)P NMR spectroscopy;;
t-BuOK-d9 in THF-d8 (tetrahydrofuran-d8) to an argon-flushed NMR tube at -95°C is given THF-d8 and t-BuOK-d9, tube is warmed to -78°C; monitored by (1)H NMR at -63°C;
triethylamine; triphenylphosphine in not given byproducts: C6H5CHO, {N(C2H5)3H}Cl; High Pressure; react. at 55°C and 80 atm H2 in presence of excess NEt3 and PPh3;; react. is monitored by high-pressure NMR; isolation and identification by NMR;;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 20 p. 3081 - 3084
