in toluene
(N2); Schlenk technique; soln. of ligand (1 equiv.) in toluene was addeddropwise to stirred suspn. of Pd complex (1 equiv.) in toluene; mixt. w as stirred at room temp. for 12 h; filtered; washed (Et2O); dried (vac.); crystd. (CH2Cl2/petroleum ether);elem. anal.;
参考文献
Lindsell, W. Edward; Palmer, Daniel D.; Preston, Peter N.; Rosair, Georgina M.; Jones, Ray V. H.; Whitton, Alan J.
Organometallics, 2005 , vol. 24, # 6 p. 1119 - 1133
in tetrahydrofuran
addn. of THF to mixt. of the ethylene and Pd-complex (stirring, room temp., 36 h; then 65°C, 7 h); filtration; crystn. of the Pd-complex from the mother-liquor;
water; caesium carbonate; (18)O2 in ethylene glycol dimethyl ether
参考文献
Wacharasindhu, Sumrit; Bardhan, Sujata; Wan, Zhao-Kui; Tabei, Keiko; Mansour, Tarek S.
Journal of the American Chemical Society, 2009 , vol. 131, p. 4174 - 4175
