2,5-二甲基-3-己炔-2,5-二醇合成路线 （共 93 条）
反应条件
potassium hydride in tetrahydrofuran T=30°C; P=759.826 Torr; 2.25 h;
参考文献
US6369282 B1, ;
Page column 3 ;
反应条件
N,N,N',N,-tetramethylethylenediamine; copper dichloride in N,N-dimethyl-formamide T=40°C; 2 h; Schlenk techniqueInert atmosphere;
参考文献
Zhang, Guanghui; Yi, Hong; Zhang, Guoting; Deng, Yi; Bai, Ruopeng; Zhang, Heng; Miller, Jeffrey T.; Kropf, Arthur J.; Bunel, Emilio E.; Lei, Aiwen
Journal of the American Chemical Society, 2014 , vol. 136, # 3 p. 924 - 926
反应条件
potassium hydroxide; calcium carbide; benzene T=20 - 24°C;
参考文献
US2250445 , ;
Journal of the American Chemical Society, , vol. 62, p. 36,43
反应条件
sodium hydroxide; tetrabutylammomium bromide in toluene T=70°C; 2 h;
参考文献
Dehmlow, Eckehard V.; Shamout, Abdul Rahman
Liebigs Annalen der Chemie, 1982 , # 9 p. 1750 - 1752
反应条件
1: 2-methyl-propan-1-ol With potassium hydride in tetrahydrofuran T=30°C; P=759.826 Torr; 0.25 h; 2: acetone; acetylene in tetrahydrofuran T=30°C; P=759.826 Torr; 2.25 h;
参考文献
US6369282 B1, ;
Page column 3 ;
反应条件
carbon monoxide; water in water; acetonitrile; benzene addn. of CAN to soln. of cumulene complex in alcohol and benzene, bubbling of CO, stirred for 4h at room temp.; diln with H2O, extn. (Et2O), chromy. (silica gel);
参考文献
Chemistry Letters, , p. 891 - 894
反应条件
1: With potassium sec-butoxide T=30 - 35°C; 2: With water 3: With phosphoric acid Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: EP1161407 B1, 2004 ;
Location in patent: Page/Page column 13; 14 ;
反应条件
potassium hydroxide in water reaction of CaC2, KOH and acetone with subsequent decompn. by H2O; mechanism discussed;;
参考文献
Zhurnal obshchei Khim. (russ.), , vol. 4, p. 1347 - 1352
Ca: MVol.B3, 89, page 845 - 848
参考文献
Chemische Berichte, , vol. 59, p. 1931,1935
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, , vol. 58, p. 1070,1076
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, , vol. 61, p. 1697
Chem. Zentralbl., , vol. 101, # I p. 3170
参考文献
Bulletin de la Societe Chimique de France, , vol. <3>30, p. 210
Chemische Berichte, , vol. 60, p. 628,638
